1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone

1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone

The title molecule, C9H7BrN4OS, is essentially planar [r.m.s. deviation = 0.066 (2) Å], the maximum deviation from the mean plane through the non-H atoms being 0.190 (3) Å for the terminal amine N atom. In the crystal, molecules are linked th...

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Main Authors: Adriano B. Oliveira, Inke Jess, Christian Näther, Leandro Bresolin, Katlen C. T. Bandeira
Format: Article
Language:English
Published: International Union of Crystallography 2013-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813018564
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spelling doaj-5c9e73ff6b1e480ab4a8064861c2b60c2020-11-24T22:26:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-08-01698o1251o125210.1107/S16005368130185641-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazoneAdriano B. OliveiraInke JessChristian NätherLeandro BresolinKatlen C. T. BandeiraThe title molecule, C9H7BrN4OS, is essentially planar [r.m.s. deviation = 0.066 (2) Å], the maximum deviation from the mean plane through the non-H atoms being 0.190 (3) Å for the terminal amine N atom. In the crystal, molecules are linked through N—H...O and N—H...S interactions, generating infinite chains along the b-axis direction. In turn, the chains are stacked along the a axis via π–π interactions [centroid–centroid distance = 3.470 (2) Å] and further connected by N—H...Br interactions into a three-dimensional network. An intramolecular N—H...O hydrogen bond is also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536813018564
collection DOAJ
language English
format Article
sources DOAJ
author Adriano B. Oliveira
Inke Jess
Christian Näther
Leandro Bresolin
Katlen C. T. Bandeira
spellingShingle Adriano B. Oliveira
Inke Jess
Christian Näther
Leandro Bresolin
Katlen C. T. Bandeira
1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone
Acta Crystallographica Section E
author_facet Adriano B. Oliveira
Inke Jess
Christian Näther
Leandro Bresolin
Katlen C. T. Bandeira
author_sort Adriano B. Oliveira
title 1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone
title_short 1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone
title_full 1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone
title_fullStr 1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone
title_full_unstemmed 1-(5-Bromo-2-oxoindolin-3-ylidene)thiosemicarbazone
title_sort 1-(5-bromo-2-oxoindolin-3-ylidene)thiosemicarbazone
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-08-01
description The title molecule, C9H7BrN4OS, is essentially planar [r.m.s. deviation = 0.066 (2) Å], the maximum deviation from the mean plane through the non-H atoms being 0.190 (3) Å for the terminal amine N atom. In the crystal, molecules are linked through N—H...O and N—H...S interactions, generating infinite chains along the b-axis direction. In turn, the chains are stacked along the a axis via π–π interactions [centroid–centroid distance = 3.470 (2) Å] and further connected by N—H...Br interactions into a three-dimensional network. An intramolecular N—H...O hydrogen bond is also observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813018564
work_keys_str_mv AT adrianoboliveira 15bromo2oxoindolin3ylidenethiosemicarbazone
AT inkejess 15bromo2oxoindolin3ylidenethiosemicarbazone
AT christiann228ther 15bromo2oxoindolin3ylidenethiosemicarbazone
AT leandrobresolin 15bromo2oxoindolin3ylidenethiosemicarbazone
AT katlenctbandeira 15bromo2oxoindolin3ylidenethiosemicarbazone
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