Síntese e emprego do ciclometalado [Pd(dmba)(N3)(PPh3)] em processos catalíticos envolvendo a n-carbonilação redutiva de nitroarenos a carbamatos e na síntese de derivados da uréia Synthesis of [Pd(dmba)(N3)(PPh3)] and its use in catalytic processes involving the reductive n-carbonylation of nitroarenes to carbamates and in the synthesis of urea derivatives

Síntese e emprego do ciclometalado [Pd(dmba)(N3)(PPh3)] em processos catalíticos envolvendo a n-carbonilação redutiva de nitroarenos a carbamatos e na síntese de derivados da uréia Synthesis of [Pd(dmba)(N3)(PPh3)] and its use in catalytic processes involving the reductive n-carbonylation of nitroarenes to carbamates and in the synthesis of urea derivatives

<abstract language="eng">This work deals with the use of the cyclometallated compound [Pd(dmba)(N3)(PPh3)] in homogeneous catalytic processes comprising the reductive N-carbonylation of nitrobenzene and p-nitrotoluene to ethyl-phenylcarbamate and ethyl-4-methylphenylcarbamate, respec...

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Bibliographic Details
Main Authors: Antonio Carlos Fávero Caires, Antonio Eduardo Mauro, Antonio Carlos Moro, Alexandre de Oliveira Legendre, Sandra Regina Ananias
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2006-07-01
Series:Química Nova
Subjects:
cyclopalladated compound
homogeneous catalytic process
reductive N-carbonylation
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422006000400022

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