Synthesis and characterization of butadiene-1,3 and octene-1 copolymer prepared by a Ziegler-Natta catalyst based on neodymium

Synthesis and characterization of butadiene-1,3 and octene-1 copolymer prepared by a Ziegler-Natta catalyst based on neodymium

The aim of this work is to evaluate the influence of octene-1 incorporation in the polybutadiene chain on the polymerization reaction and polymer characteristics. Thus, copolymerization of butadiene-1,3 with octene-1 using a Ziegler-Natta ternary catalyst based on neodymium was performed. The weight...

Full description

Bibliographic Details
Main Authors:	Gustavo M. Silva, Fernanda M. B. Coutinho, Ivana L. Mello, Marcos A. S. Costa, Daniele F. C. Junger
Format:	Article
Language:	English
Published:	Associação Brasileira de Polímeros 2011-01-01
Series:	Polímeros
Subjects:	High-cis polybutadiene copolymerization octene-1 Ziegler-Natta catalyst
Online Access:	http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282011000400012

Similar Items

Influência do envelhecimento de catalisadores Ziegler-Natta à base de neodímio sobre a polimerização de 1,3-butadieno Influence of ageing of neodymium based Ziegler-Natta catalyst on butadiene polymerization
by: Ivana L. Mello, et al.
Published: (2007-03-01)

Polimerização 1,4-cis de butadieno com sistemas catalíticos Ziegler-Natta à base de neodímio
by: Mello Ivana L., et al.
Published: (2004-01-01)

Efeito de doadores de elétrons na polimerização de butadieno com catalisadores à base de neodímio Effect of electron donors on the polymerization of butadiene with Ziegler-Natta catalysts based on neodymium
by: Tereza C. J. Rocha, et al.
Published: (2005-03-01)

Principais aspectos da polimerização do 1,3-butadieno Principles aspects of butadiene 1,3 polymerization
by: Denise S. S. Nunes, et al.
Published: (2005-11-01)

Influência do agente de cloração do catalisador à base de veodímio e da razão molar Cl: Nd na polimerização do butadieno Influence of the chlorinating agent of neodymium based catalysts and Cl: Nd molar ratio on butadiene polymerization
by: Cintia N. Ferreira, et al.
Published: (2009-06-01)

Study of ethylene/propylene polymerization, using a 4th generation Ziegler-Natta catalyst: Effect of external donor and feed ratio on polymerization
by: Shafagh Dehghani, Seyedeh
Published: (2012)

Polimerização 1,4 - cis de butadieno com o sistema catalítico tetracloreto de titânio/triisobutilalumínio/iodo 1,4 cis-Polymerization of butadiene by the catalyst system titanium tetrachloride/triisobutylaluminium/iodine
by: Neusa M. T. Pires, et al.
Published: (2000-12-01)

Síntese de catalisadores Ziegler-Natta: algumas rotas e suas dificuldades Synthesis of Ziegler-Natta catalysts: some routes and their difficulties
by: Thaís H. S. Costa, et al.
Published: (1997-02-01)

In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst
by: Maria Marques, et al.
Published: (2014-01-01)

Copolymerization of Ethylene and Propylene Using 4th Generation Ziegler- Natta Catalyst: Influence of Cocatalyst, External Electron Donor and Hydrogen
by: R. Mehtarani, et al.
Published: (2007-08-01)

Imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalysts for ethylene polymerization and ethylene/1-hexene copolymerization
by: Ting Fu, et al.
Published: (2016-06-01)

The Influence of Ziegler-Natta and Metallocene Catalysts on Polyolefin Structure, Properties, and Processing Ability
by: Ahmad Shamiri, et al.
Published: (2014-07-01)

fecto del electrodonador externo y la prepolimerización sobre el rendimiento de catalizadores Ziegler-Natta en la polimerización de propileno Effect of external donor and prepolymerization on the performance of Ziegler-Natta catalysts in propylene polymerization
by: Francisco Osorio, et al.
Published: (2009-08-01)

Influência do agente de halogenação e da razão molar Cl:Nd na polimerização e nas características do polibutadieno obtido com catalisador Ziegler-Natta à base de neodímio
by: Cíntia Nogueira Ferreira
Published: (2008)

Influência do agente de halogenação e da razão molar Cl:Nd na polimerização e nas características do polibutadieno obtido com catalisador Ziegler-Natta à base de neodímio
by: Cíntia Nogueira Ferreira
Published: (2008)

Preparation and investigation of model surfaces for the study of Ziegler-natta catalysis
by: Mischenko, John
Published: (2013)

Copolymerization of 1-hexene and 1-dodecene with 1,3-butadiene by a versatate/diisobutylaluminum hydride/t-butyl chloride catalyst system
by: Gustavo Monteiro da Silva, et al.
Published: (2014-01-01)

Preparação, caracterização e aplicação de catalisadores Ziegler-Natta na produção de polietileno de alta densidade
by: Wolf, Carlos Rodolfo
Published: (2015)

Preparação, caracterização e aplicação de catalisadores Ziegler-Natta na produção de polietileno de alta densidade
by: Wolf, Carlos Rodolfo
Published: (2015)

Preparação, caracterização e aplicação de catalisadores Ziegler-Natta na produção de polietileno de alta densidade
by: Wolf, Carlos Rodolfo
Published: (2015)

An Investigation on Polymerization of Ethylene by Ziegler-Natta Catalyst in the Presence of a Promoter: Polymerization Behavior and Polymer Microstructure
by: Yaghoob Gholami, et al.
Published: (2018-12-01)

The Use of Electron Donors to Increase Stereospecificity in Ziegler-Natta Propylene Polymerization
by: Farshid Nouri-Ahangarani, et al.
Published: (2016-05-01)

Addition of a second alcohol in magnesium ethoxide synthesis as a way to vary the pore architecture of Ziegler-Natta catalysts
by: Toshiaki Funako, et al.
Published: (2015-06-01)

Probing into morphology evolution of magnesium ethoxide particles as precursor of Ziegler-Natta catalysts
by: Goond Hongmanee, et al.
Published: (2016-01-01)

Effects of various poisoning compounds on the activity and stereospecificity of heterogeneous Ziegler–Natta catalyst
by: Kitti Tangjituabun et al
Published: (2008-01-01)

Σύνθεση ρεαλιστικών προτύπων προδρόμων καταλυτικών συστημάτων Ziegler - Natta και διερεύνηση της επίδρασης του παράγοντα αλκυλίωσης: μελέτη με φασματοσκοπία φωτοηλεκτρονίων από ακτίνες Χ
by: Νταής, Σπύρος Η.
Published: (2010)

Preparation of MgCl<sub>2</sub>-Supported Ziegler-Natta Catalysts via New Surfactants Emulsion for Propylene Polymerization
by: Yansong Wu, et al.
Published: (2021-05-01)

CATALIZADORES Ziegler-Natta utilizados para polimerizar propileno y etileno
by: Castro, Carlos A., et al.
Published: (2017)

Uma revisão sobre polimerização de olefinas usando catalisadores Ziegler-Natta heterogêneos A survey on olefins polymerization using heterogeneous Ziegler-Natta catalysts
by: Fabricio Machado, et al.
Published: (2011-01-01)

Gas-phase ethylene polymerization studies using a magnesium chloride-supported Ziegler-Natta catalyst.
by: Naicker, Omasha.
Published: (2010)

Síntese e caracterização de copolímeros de propeno com 1-hexeno e 1,5-hexadieno Synthesis and characterization of propylene/1-hexene and propylene/1,5-hexadiene copolymers
by: Aline F. Lima, et al.
Published: (2012-01-01)

Comparative Study on Kinetics of Ethylene and Propylene Polymerizations with Supported Ziegler–Natta Catalyst: Catalyst Fragmentation Promoted by Polymer Crystalline Lamellae
by: Zhen Zhang, et al.
Published: (2019-02-01)

fecto del electrodonador externo y la prepolimerización sobre el rendimiento de catalizadores Ziegler-Natta en la polimerización de propileno
by: Francisco Osorio, et al.

The Influence of Mixed Activators on Ethylene Polymerization and Ethylene/1-Hexene Copolymerization with Silica-Supported Ziegler-Natta Catalyst
by: Piyasan Praserthdam, et al.
Published: (2010-12-01)

How can pH value during catalyst preparation affect the performance of vanadium-modified (SiO2/MgO/ MgCl2)•TiClx Ziegler-Natta polyethylene catalysts
by: Ting Fu, et al.
Published: (2018-01-01)

Study of Slurry Ethylene Polymerization with Ziegler-Natta Catalysts: Kinetics and Investigation on the Rate of Monomer Consumption Equation
by: M. Salami-Kalajahi, et al.
Published: (2008-02-01)

1-Hexene Polymerization Using Ziegler-Natta Catalytic System with Response Surface Methodology
by: Maliheh Mazaheriyan, et al.
Published: (2017-07-01)

Sixtieth Anniversary of Ziegler-Natta Catalysts and Stereospecific Polymerization
by: Janović Z., et al.
Published: (2015-07-01)

Estudo da polimerização do 2-metil, 1,3-butadieno via catalisadores lantanídicos: influência do tipo de alquilalumínio, da temperatura reacional e da concentração do catalisador Polymerization of 2-methyl, 1,3-butadiene via lanthanides catalysts: influence from the type of alkylaluminum, concentration and reaction temperature and catalyst
by: André L. C. Simões, et al.
Published: (2011-01-01)

MgCl2 Support Preparation Techniques and Their Effects on Ziegler-Natta Catalysts Performance in Propylene Polymerization
by: Najmeh Hadian, et al.
Published: (2013-08-01)