Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium
In the crystal structure of the title compound, [Ru3(C9H11P)H2(C18H15P)(CO)8], the triangular Ru3 unit is capped with one mesitylphosphinidene ligand. In the trigonal–pyramidal Ru3P core, one RuII atom is coordinated by a triphenylphosphane ligand in a terminal fashion. Two hydride lig...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812039499 |
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doaj-5c3fc1b7a7aa43b6956d2f7e9bfa5dc02020-11-24T20:48:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1293m129310.1107/S1600536812039499Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-trirutheniumTaeko KakizawaIn the crystal structure of the title compound, [Ru3(C9H11P)H2(C18H15P)(CO)8], the triangular Ru3 unit is capped with one mesitylphosphinidene ligand. In the trigonal–pyramidal Ru3P core, one RuII atom is coordinated by a triphenylphosphane ligand in a terminal fashion. Two hydride ligands bridge over two Ru—Ru bonds. These Ru—Ru bonds [2.9400 (4) and 2.9432 (4) Å] are slightly longer than the nonhydride-bridged Ru—Ru bond [2.8146 (4) Å]. The terminal triphenylphosphane ligand coordinates to the RuII atom, which is involved in two hydride bridges.http://scripts.iucr.org/cgi-bin/paper?S1600536812039499 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Taeko Kakizawa |
| spellingShingle |
Taeko Kakizawa Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium Acta Crystallographica Section E |
| author_facet |
Taeko Kakizawa |
| author_sort |
Taeko Kakizawa |
| title |
Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_short |
Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_full |
Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_fullStr |
Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_full_unstemmed |
Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_sort |
octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-10-01 |
| description |
In the crystal structure of the title compound, [Ru3(C9H11P)H2(C18H15P)(CO)8], the triangular Ru3 unit is capped with one mesitylphosphinidene ligand. In the trigonal–pyramidal Ru3P core, one RuII atom is coordinated by a triphenylphosphane ligand in a terminal fashion. Two hydride ligands bridge over two Ru—Ru bonds. These Ru—Ru bonds [2.9400 (4) and 2.9432 (4) Å] are slightly longer than the nonhydride-bridged Ru—Ru bond [2.8146 (4) Å]. The terminal triphenylphosphane ligand coordinates to the RuII atom, which is involved in two hydride bridges. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812039499 |
| work_keys_str_mv |
AT taekokakizawa octacarbonyldiamp9562hydridoamp9563135trimethylphenylphosphinidenetriphenylphosphanetriangulotriruthenium |
| _version_ |
1716807531450335232 |