Bis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrate

Bis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrate

The Co ion in the title salt, [Co(NO3)(H2NCH2CH2NH2)2](OH)(NO3), has oxidation state + III and is coordinated by four N atoms from two ethylenediamine molecules and two O atoms from a nitrate anion in a distorted octahedral geometry. The charge of the complex cation is balanced by a hydroxide anion...

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Main Authors: Ji-Bo Zhang, Xiao-Shu Qu
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680903219X
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spelling doaj-5c2470fdc78b4787b44a93760e3b20432020-11-25T01:35:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1099m110010.1107/S160053680903219XBis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrateJi-Bo ZhangXiao-Shu QuThe Co ion in the title salt, [Co(NO3)(H2NCH2CH2NH2)2](OH)(NO3), has oxidation state + III and is coordinated by four N atoms from two ethylenediamine molecules and two O atoms from a nitrate anion in a distorted octahedral geometry. The charge of the complex cation is balanced by a hydroxide anion and a nitrate anion. The cations and anions are connected by N—H...O and O—H...O hydrogen bonds, resulting in a three-dimensional supramolecular framework. There are two independent ion pairs with similar configurations in the unit cell. Both uncoordinated nitrate counter-anions are disordered. http://scripts.iucr.org/cgi-bin/paper?S160053680903219X
collection DOAJ
language English
format Article
sources DOAJ
author Ji-Bo Zhang
Xiao-Shu Qu
spellingShingle Ji-Bo Zhang
Xiao-Shu Qu
Bis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrate
Acta Crystallographica Section E
author_facet Ji-Bo Zhang
Xiao-Shu Qu
author_sort Ji-Bo Zhang
title Bis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrate
title_short Bis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrate
title_full Bis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrate
title_fullStr Bis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrate
title_full_unstemmed Bis(ethylenediamine-κ2N,N′)(nitrato-κ2O,O′)cobalt(III) hydroxide nitrate
title_sort bis(ethylenediamine-κ2n,n′)(nitrato-κ2o,o′)cobalt(iii) hydroxide nitrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description The Co ion in the title salt, [Co(NO3)(H2NCH2CH2NH2)2](OH)(NO3), has oxidation state + III and is coordinated by four N atoms from two ethylenediamine molecules and two O atoms from a nitrate anion in a distorted octahedral geometry. The charge of the complex cation is balanced by a hydroxide anion and a nitrate anion. The cations and anions are connected by N—H...O and O—H...O hydrogen bonds, resulting in a three-dimensional supramolecular framework. There are two independent ion pairs with similar configurations in the unit cell. Both uncoordinated nitrate counter-anions are disordered.
url http://scripts.iucr.org/cgi-bin/paper?S160053680903219X
work_keys_str_mv AT jibozhang bisethylenediamineamp9542nnamp8242nitratoamp9542ooamp8242cobaltiiihydroxidenitrate
AT xiaoshuqu bisethylenediamineamp9542nnamp8242nitratoamp9542ooamp8242cobaltiiihydroxidenitrate
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