N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide

N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide

In the title compound, C26H24Cl4N2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide group...

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Main Authors: Tahir Ali Sheikh, Ejaz, Islam Ullah Khan, William T. A. Harrison
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811045478
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spelling doaj-5bd86f4dfe1447e5b3a43e3ec9b3ab5a2020-11-25T02:24:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712o3280o328010.1107/S1600536811045478N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamideTahir Ali SheikhEjazIslam Ullah KhanWilliam T. A. HarrisonIn the title compound, C26H24Cl4N2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide groups lie to the same side of the central ring but the pendant chains have very different conformations, as indicated by their C—S—N—C torsion angles [104.66 (17) and −76.35 (19)°] and S—N—C—C torsion angles [129.61 (17) and 147.10 (17)°]. Both N atoms are close to planar (bond angle sums = 359.0 and 354.8°). In the crystal, inversion dimers are formed via a pair of weak C—H...O interactions which generate R22(22) loops.http://scripts.iucr.org/cgi-bin/paper?S1600536811045478
collection DOAJ
language English
format Article
sources DOAJ
author Tahir Ali Sheikh
Ejaz
Islam Ullah Khan
William T. A. Harrison
spellingShingle Tahir Ali Sheikh
Ejaz
Islam Ullah Khan
William T. A. Harrison
N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide
Acta Crystallographica Section E
author_facet Tahir Ali Sheikh
Ejaz
Islam Ullah Khan
William T. A. Harrison
author_sort Tahir Ali Sheikh
title N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide
title_short N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide
title_full N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide
title_fullStr N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide
title_full_unstemmed N,N′-Diallyl-2,2′,5,5′-tetrachloro-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide
title_sort n,n′-diallyl-2,2′,5,5′-tetrachloro-n,n′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-12-01
description In the title compound, C26H24Cl4N2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 70.07 (12) and 59.07 (12)°. The equivalent angle between the pendant rings is 79.24 (12)°. Both sulfonamide groups lie to the same side of the central ring but the pendant chains have very different conformations, as indicated by their C—S—N—C torsion angles [104.66 (17) and −76.35 (19)°] and S—N—C—C torsion angles [129.61 (17) and 147.10 (17)°]. Both N atoms are close to planar (bond angle sums = 359.0 and 354.8°). In the crystal, inversion dimers are formed via a pair of weak C—H...O interactions which generate R22(22) loops.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811045478
work_keys_str_mv AT tahiralisheikh nnamp8242diallyl22amp824255amp8242tetrachloronnamp824213phenylenebismethylenedibenzenesulfonamide
AT ejaz nnamp8242diallyl22amp824255amp8242tetrachloronnamp824213phenylenebismethylenedibenzenesulfonamide
AT islamullahkhan nnamp8242diallyl22amp824255amp8242tetrachloronnamp824213phenylenebismethylenedibenzenesulfonamide
AT williamtaharrison nnamp8242diallyl22amp824255amp8242tetrachloronnamp824213phenylenebismethylenedibenzenesulfonamide
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