Synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (II) with transition metal (Ni (II), Pd (II), and Pt (II))
Treatment of 2-Mercaptobenzimidazol (HL) with the mercuric acetate (Hg(OAc)2) give the complex[Hg(L)2] (1). Then the multinuclear complexes of the type [M2Hg2(L)4Cl4] were prepared through the reaction of complex (1) with each of NiCl2.6H2O, PdCl2 and PtCl2 in (2:2) molar ratio. All complexes were...
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Salahaddin University-Erbil
2020-02-01
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| Online Access: | https://zancojournals.su.edu.krd/index.php/JPAS/article/view/2773 |
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doaj-5b81cb83b4bd4c7db888fe48619386f42020-11-25T02:05:32ZengSalahaddin University-ErbilZanco Journal of Pure and Applied Sciences2218-02302412-39862020-02-0132110410910.21271/zjpas.32.1.11Synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (II) with transition metal (Ni (II), Pd (II), and Pt (II))Nhiyat Hassan0Hikmat A. Mohammad1Department of Chemistry, College of Education, University of Salahaddin-Erbil, Kurdistan Region, IraqDepartment of Chemistry, College of Education, University of Salahaddin-Erbil, Kurdistan Region, Iraq Treatment of 2-Mercaptobenzimidazol (HL) with the mercuric acetate (Hg(OAc)2) give the complex[Hg(L)2] (1). Then the multinuclear complexes of the type [M2Hg2(L)4Cl4] were prepared through the reaction of complex (1) with each of NiCl2.6H2O, PdCl2 and PtCl2 in (2:2) molar ratio. All complexes were described using infrared spectra, Proton Nuclear Magnetic Resonance , Carbon 13- Nuclear Magnetic Resonance , ultraviolet-visible, atomic absorption spectroscopy, CHNS analysis, molar conductivity, determination of Chloride Percentage and magnetic susceptibility measurements.The heterocyclic ligand is expected to be coordinated to two or single metal atom through the nitrogen atom and sulphur atom or by only sulphur atom.https://zancojournals.su.edu.krd/index.php/JPAS/article/view/27732-mercapto benzimidazole: ni (ii)pd (ii)pt (ii)hg(ii). |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Nhiyat Hassan Hikmat A. Mohammad |
| spellingShingle |
Nhiyat Hassan Hikmat A. Mohammad Synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (II) with transition metal (Ni (II), Pd (II), and Pt (II)) Zanco Journal of Pure and Applied Sciences 2-mercapto benzimidazole: ni (ii) pd (ii) pt (ii) hg(ii). |
| author_facet |
Nhiyat Hassan Hikmat A. Mohammad |
| author_sort |
Nhiyat Hassan |
| title |
Synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (II) with transition metal (Ni (II), Pd (II), and Pt (II)) |
| title_short |
Synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (II) with transition metal (Ni (II), Pd (II), and Pt (II)) |
| title_full |
Synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (II) with transition metal (Ni (II), Pd (II), and Pt (II)) |
| title_fullStr |
Synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (II) with transition metal (Ni (II), Pd (II), and Pt (II)) |
| title_full_unstemmed |
Synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (II) with transition metal (Ni (II), Pd (II), and Pt (II)) |
| title_sort |
synthesis and characterization complexes of bis (2-mercaptobenzimidazole) mercury (ii) with transition metal (ni (ii), pd (ii), and pt (ii)) |
| publisher |
Salahaddin University-Erbil |
| series |
Zanco Journal of Pure and Applied Sciences |
| issn |
2218-0230 2412-3986 |
| publishDate |
2020-02-01 |
| description |
Treatment of 2-Mercaptobenzimidazol (HL) with the mercuric acetate (Hg(OAc)2) give the complex[Hg(L)2] (1). Then the multinuclear complexes of the type [M2Hg2(L)4Cl4] were prepared through the reaction of complex (1) with each of NiCl2.6H2O, PdCl2 and PtCl2 in (2:2) molar ratio. All complexes were described using infrared spectra, Proton Nuclear Magnetic Resonance , Carbon 13- Nuclear Magnetic Resonance , ultraviolet-visible, atomic absorption spectroscopy, CHNS analysis, molar conductivity, determination of Chloride Percentage and magnetic susceptibility measurements.The heterocyclic ligand is expected to be coordinated to two or single metal atom through the nitrogen atom and sulphur atom or by only sulphur atom. |
| topic |
2-mercapto benzimidazole: ni (ii) pd (ii) pt (ii) hg(ii). |
| url |
https://zancojournals.su.edu.krd/index.php/JPAS/article/view/2773 |
| work_keys_str_mv |
AT nhiyathassan synthesisandcharacterizationcomplexesofbis2mercaptobenzimidazolemercuryiiwithtransitionmetalniiipdiiandptii AT hikmatamohammad synthesisandcharacterizationcomplexesofbis2mercaptobenzimidazolemercuryiiwithtransitionmetalniiipdiiandptii |
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1724937623548461056 |