Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate

Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate

The title compound, C17H29NO4, contains a chiral center and crystallizes as a racemate. The asymmetric unit consists of two non-equivalent molecules, in which the carbethoxy groups have markedly different orientations [C(=O)CC(OEt)=O torsion angles = 59.3 (2) and 156.0 (2)&#1...

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Main Authors: Gerald M. Rosen, Sukumaran Muralidharan, Peter Y. Zavalij, Steven Fletcher, Joseph P. Y. Kao
Format: Article
Language:English
Published: International Union of Crystallography 2013-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813012282
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spelling doaj-5b5760df387349e79753f7b5763b8d3c2020-11-25T01:36:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-06-01696o878o87810.1107/S1600536813012282Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylateGerald M. RosenSukumaran MuralidharanPeter Y. ZavalijSteven FletcherJoseph P. Y. KaoThe title compound, C17H29NO4, contains a chiral center and crystallizes as a racemate. The asymmetric unit consists of two non-equivalent molecules, in which the carbethoxy groups have markedly different orientations [C(=O)CC(OEt)=O torsion angles = 59.3 (2) and 156.0 (2)°]. In the crystal, molecules form chains along [101] through N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536813012282
collection DOAJ
language English
format Article
sources DOAJ
author Gerald M. Rosen
Sukumaran Muralidharan
Peter Y. Zavalij
Steven Fletcher
Joseph P. Y. Kao
spellingShingle Gerald M. Rosen
Sukumaran Muralidharan
Peter Y. Zavalij
Steven Fletcher
Joseph P. Y. Kao
Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate
Acta Crystallographica Section E
author_facet Gerald M. Rosen
Sukumaran Muralidharan
Peter Y. Zavalij
Steven Fletcher
Joseph P. Y. Kao
author_sort Gerald M. Rosen
title Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate
title_short Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate
title_full Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate
title_fullStr Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate
title_full_unstemmed Ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate
title_sort ethyl 2,5-di-tert-butyl-5-ethoxy-4-oxo-4,5-dihydro-1h-pyrrole-3-carboxylate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-06-01
description The title compound, C17H29NO4, contains a chiral center and crystallizes as a racemate. The asymmetric unit consists of two non-equivalent molecules, in which the carbethoxy groups have markedly different orientations [C(=O)CC(OEt)=O torsion angles = 59.3 (2) and 156.0 (2)°]. In the crystal, molecules form chains along [101] through N—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813012282
work_keys_str_mv AT geraldmrosen ethyl25ditertbutyl5ethoxy4oxo45dihydro1hpyrrole3carboxylate
AT sukumaranmuralidharan ethyl25ditertbutyl5ethoxy4oxo45dihydro1hpyrrole3carboxylate
AT peteryzavalij ethyl25ditertbutyl5ethoxy4oxo45dihydro1hpyrrole3carboxylate
AT stevenfletcher ethyl25ditertbutyl5ethoxy4oxo45dihydro1hpyrrole3carboxylate
AT josephpykao ethyl25ditertbutyl5ethoxy4oxo45dihydro1hpyrrole3carboxylate
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