Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}

Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}

In the centrosymmetric dinuclear title compound, [Cd2I4(C12H12N2O2)2], two μ-I atoms bridge two CdII atoms and each CdII atom is also bonded to a terminal I atom and a hydroxy-methoxy-bis(2-pyridyl)methane ligand, which functions in an N,O,N′-tridentate mode, resulting in...

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Main Authors: Majid Esmhosseini, Nasser Safari, Vahid Amani
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810041681
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spelling doaj-5b49557e89ef4700a99bec589b932e2b2020-11-24T20:48:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1434m143510.1107/S1600536810041681Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}Majid EsmhosseiniNasser SafariVahid AmaniIn the centrosymmetric dinuclear title compound, [Cd2I4(C12H12N2O2)2], two μ-I atoms bridge two CdII atoms and each CdII atom is also bonded to a terminal I atom and a hydroxy-methoxy-bis(2-pyridyl)methane ligand, which functions in an N,O,N′-tridentate mode, resulting in a distorted octahedral coordination environment. Intermolecular O—H...I hydrogen bonds and π–π stacking interactions between the pyridine rings [centroid–centroid distance = 3.790 (2) Å] are present in the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810041681
collection DOAJ
language English
format Article
sources DOAJ
author Majid Esmhosseini
Nasser Safari
Vahid Amani
spellingShingle Majid Esmhosseini
Nasser Safari
Vahid Amani
Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}
Acta Crystallographica Section E
author_facet Majid Esmhosseini
Nasser Safari
Vahid Amani
author_sort Majid Esmhosseini
title Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}
title_short Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}
title_full Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}
title_fullStr Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}
title_full_unstemmed Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3N,O,N′]iodidocadmium(II)}
title_sort di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κ3n,o,n′]iodidocadmium(ii)}
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-11-01
description In the centrosymmetric dinuclear title compound, [Cd2I4(C12H12N2O2)2], two μ-I atoms bridge two CdII atoms and each CdII atom is also bonded to a terminal I atom and a hydroxy-methoxy-bis(2-pyridyl)methane ligand, which functions in an N,O,N′-tridentate mode, resulting in a distorted octahedral coordination environment. Intermolecular O—H...I hydrogen bonds and π–π stacking interactions between the pyridine rings [centroid–centroid distance = 3.790 (2) Å] are present in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810041681
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AT nassersafari diamp956iodidobishydroxymethoxybis2pyridylmethaneamp9543nonamp8242iodidocadmiumii
AT vahidamani diamp956iodidobishydroxymethoxybis2pyridylmethaneamp9543nonamp8242iodidocadmiumii
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