catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]

catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]

In the title compound, {[Cu(C10H14N4Se)2](ClO4)2}n, the CuII ion is located on a twofold rotation axis and has a tetragonally distorted square-planar geometry constituted by four N atoms. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide (L) ligands bridges the copper centers into a polymeric cha...

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Main Authors: Maksym Seredyuk, Matti Haukka, Vadim A. Pavlenko, Igor O. Fritsky
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809042056
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spelling doaj-5ad791bfc8934cc0a134c1e4993b8c3d2020-11-25T01:13:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1396m139610.1107/S1600536809042056catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]Maksym SeredyukMatti HaukkaVadim A. PavlenkoIgor O. FritskyIn the title compound, {[Cu(C10H14N4Se)2](ClO4)2}n, the CuII ion is located on a twofold rotation axis and has a tetragonally distorted square-planar geometry constituted by four N atoms. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide (L) ligands bridges the copper centers into a polymeric chain extending along [001]. The perchlorate anions are involved in intermolecular N—H...O hydrogen bonding, which links the chains into layers parallel to the bc plane. http://scripts.iucr.org/cgi-bin/paper?S1600536809042056
collection DOAJ
language English
format Article
sources DOAJ
author Maksym Seredyuk
Matti Haukka
Vadim A. Pavlenko
Igor O. Fritsky
spellingShingle Maksym Seredyuk
Matti Haukka
Vadim A. Pavlenko
Igor O. Fritsky
catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
Acta Crystallographica Section E
author_facet Maksym Seredyuk
Matti Haukka
Vadim A. Pavlenko
Igor O. Fritsky
author_sort Maksym Seredyuk
title catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_short catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_full catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_fullStr catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_full_unstemmed catena-Poly[[copper(II)-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(perchlorate)]
title_sort catena-poly[[copper(ii)-bis[μ-bis(3,5-dimethyl-1h-pyrazol-4-yl) selenide]] bis(perchlorate)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description In the title compound, {[Cu(C10H14N4Se)2](ClO4)2}n, the CuII ion is located on a twofold rotation axis and has a tetragonally distorted square-planar geometry constituted by four N atoms. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide (L) ligands bridges the copper centers into a polymeric chain extending along [001]. The perchlorate anions are involved in intermolecular N—H...O hydrogen bonding, which links the chains into layers parallel to the bc plane.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809042056
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AT mattihaukka catenapolycopperiibisamp956bis35dimethyl1hpyrazol4ylselenidebisperchlorate
AT vadimapavlenko catenapolycopperiibisamp956bis35dimethyl1hpyrazol4ylselenidebisperchlorate
AT igorofritsky catenapolycopperiibisamp956bis35dimethyl1hpyrazol4ylselenidebisperchlorate
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