Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines

Despite their higher abundance, 3d metal-based catalysts are less investigated than their precious metal counterparts. Here, the authors report a cobalt-triphos complex as molecularly-defined non-noble metal catalyst for the reductive amination of carbonyl compounds with gaseous ammonia and hydrogen...

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Main Authors:	Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Helfried Neumann, Anke Spannenberg, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-11-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-13351-7

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spelling	doaj-5ab10d284af5402ab16da0d410af6a0e2021-05-11T12:03:12ZengNature Publishing GroupNature Communications2041-17232019-11-011011910.1038/s41467-019-13351-7Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary aminesKathiravan Murugesan0Zhihong Wei1Vishwas G. Chandrashekhar2Helfried Neumann3Anke Spannenberg4Haijun Jiao5Matthias Beller6Rajenahally V. Jagadeesh7Leibniz-Institut für Katalyse e.V. an der Universität RostockLeibniz-Institut für Katalyse e.V. an der Universität RostockLeibniz-Institut für Katalyse e.V. an der Universität RostockLeibniz-Institut für Katalyse e.V. an der Universität RostockLeibniz-Institut für Katalyse e.V. an der Universität RostockLeibniz-Institut für Katalyse e.V. an der Universität RostockLeibniz-Institut für Katalyse e.V. an der Universität RostockLeibniz-Institut für Katalyse e.V. an der Universität RostockDespite their higher abundance, 3d metal-based catalysts are less investigated than their precious metal counterparts. Here, the authors report a cobalt-triphos complex as molecularly-defined non-noble metal catalyst for the reductive amination of carbonyl compounds with gaseous ammonia and hydrogen.https://doi.org/10.1038/s41467-019-13351-7
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Kathiravan Murugesan Zhihong Wei Vishwas G. Chandrashekhar Helfried Neumann Anke Spannenberg Haijun Jiao Matthias Beller Rajenahally V. Jagadeesh
spellingShingle	Kathiravan Murugesan Zhihong Wei Vishwas G. Chandrashekhar Helfried Neumann Anke Spannenberg Haijun Jiao Matthias Beller Rajenahally V. Jagadeesh Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines Nature Communications
author_facet	Kathiravan Murugesan Zhihong Wei Vishwas G. Chandrashekhar Helfried Neumann Anke Spannenberg Haijun Jiao Matthias Beller Rajenahally V. Jagadeesh
author_sort	Kathiravan Murugesan
title	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_short	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_full	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_fullStr	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_full_unstemmed	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_sort	homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-11-01
description	Despite their higher abundance, 3d metal-based catalysts are less investigated than their precious metal counterparts. Here, the authors report a cobalt-triphos complex as molecularly-defined non-noble metal catalyst for the reductive amination of carbonyl compounds with gaseous ammonia and hydrogen.
url	https://doi.org/10.1038/s41467-019-13351-7
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Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines

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