trans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)

In the title compound, [PdBr2(C19H17P)2], the PdII ion resides on a centre of symmetry and is coordinated by two Br anions [Pd—Br = 2.4266 (2) Å] and two P-donor ligands [Pd—P = 2.3462 (5) Å...

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Main Authors: Andreas Roodt, Gideon Steyl, Leo Kirsten
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809045401
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spelling doaj-5a7cd9e340f34d8586d8a526e333c22a2020-11-25T01:36:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1564m156410.1107/S1600536809045401trans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)Andreas RoodtGideon SteylLeo KirstenIn the title compound, [PdBr2(C19H17P)2], the PdII ion resides on a centre of symmetry and is coordinated by two Br anions [Pd—Br = 2.4266 (2) Å] and two P-donor ligands [Pd—P = 2.3462 (5) Å] in a slightly distorted square-planar geometry [P—Pd—Br = 93.528 (12)°]. Weak intermolecular C—H...Br hydrogen bonds link molecules into chains extended in [1overline{1}0]. http://scripts.iucr.org/cgi-bin/paper?S1600536809045401
collection DOAJ
language English
format Article
sources DOAJ
author Andreas Roodt
Gideon Steyl
Leo Kirsten
spellingShingle Andreas Roodt
Gideon Steyl
Leo Kirsten
trans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)
Acta Crystallographica Section E
author_facet Andreas Roodt
Gideon Steyl
Leo Kirsten
author_sort Andreas Roodt
title trans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)
title_short trans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)
title_full trans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)
title_fullStr trans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)
title_full_unstemmed trans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)
title_sort trans-dibromidobis[diphenyl(p-tolyl)phosphine]palladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description In the title compound, [PdBr2(C19H17P)2], the PdII ion resides on a centre of symmetry and is coordinated by two Br anions [Pd—Br = 2.4266 (2) Å] and two P-donor ligands [Pd—P = 2.3462 (5) Å] in a slightly distorted square-planar geometry [P—Pd—Br = 93.528 (12)°]. Weak intermolecular C—H...Br hydrogen bonds link molecules into chains extended in [1overline{1}0].
url http://scripts.iucr.org/cgi-bin/paper?S1600536809045401
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AT gideonsteyl transdibromidobisdiphenylptolylphosphinepalladiumii
AT leokirsten transdibromidobisdiphenylptolylphosphinepalladiumii
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