Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc

Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc

The mononuclear zinc title complex, [Zn(C20H22N2O4)(H2O)], was obtained by the reaction of 3-ethoxysalicylaldehyde, ethane-1,2-diamine, and zinc acetate in methanol. The Zn atom is five-coordinated by two phenolate O and two imine N atoms of the tetradentate Schiff base ligand and by one water O ato...

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Main Authors: Chen-Yi Wang, Xiang Wu, Juan-Juan Hu, Zhi-Ping Han
Format: Article
Language:English
Published: International Union of Crystallography 2011-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811031497
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spelling doaj-5a3395a090bd4e06993566d4b6c722242020-11-25T02:40:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679m1220m122010.1107/S1600536811031497Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zincChen-Yi WangXiang WuJuan-Juan HuZhi-Ping HanThe mononuclear zinc title complex, [Zn(C20H22N2O4)(H2O)], was obtained by the reaction of 3-ethoxysalicylaldehyde, ethane-1,2-diamine, and zinc acetate in methanol. The Zn atom is five-coordinated by two phenolate O and two imine N atoms of the tetradentate Schiff base ligand and by one water O atom, forming a square-pyramidal geometry. In the crystal, pairs of molecules are linked via intermolecular O—H...O hydrogen bonds, forming dimers.http://scripts.iucr.org/cgi-bin/paper?S1600536811031497
collection DOAJ
language English
format Article
sources DOAJ
author Chen-Yi Wang
Xiang Wu
Juan-Juan Hu
Zhi-Ping Han
spellingShingle Chen-Yi Wang
Xiang Wu
Juan-Juan Hu
Zhi-Ping Han
Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc
Acta Crystallographica Section E
author_facet Chen-Yi Wang
Xiang Wu
Juan-Juan Hu
Zhi-Ping Han
author_sort Chen-Yi Wang
title Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc
title_short Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc
title_full Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc
title_fullStr Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc
title_full_unstemmed Aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc
title_sort aqua{6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}zinc
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-09-01
description The mononuclear zinc title complex, [Zn(C20H22N2O4)(H2O)], was obtained by the reaction of 3-ethoxysalicylaldehyde, ethane-1,2-diamine, and zinc acetate in methanol. The Zn atom is five-coordinated by two phenolate O and two imine N atoms of the tetradentate Schiff base ligand and by one water O atom, forming a square-pyramidal geometry. In the crystal, pairs of molecules are linked via intermolecular O—H...O hydrogen bonds, forming dimers.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811031497
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AT xiangwu aqua66amp8242diethoxy22amp8242ethane12diylbisnitrilomethanylylidenediphenolatozinc
AT juanjuanhu aqua66amp8242diethoxy22amp8242ethane12diylbisnitrilomethanylylidenediphenolatozinc
AT zhipinghan aqua66amp8242diethoxy22amp8242ethane12diylbisnitrilomethanylylidenediphenolatozinc
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