Methanoldioxido{1-[(2RS)-(2-oxidopropyl)iminomethyl]-2-naphtholato}molybdenium(VI)
Crystals of the title compound, [Mo(C14H13NO2)O2(CH4O)], were obtained by recrystallization from methanol. The MoVI atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidopropyl)iminomethyl]-2-naphtholate Schiff base ligand. The coordination sphere is...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681000262X |
| Summary: | Crystals of the title compound, [Mo(C14H13NO2)O2(CH4O)], were obtained by recrystallization from methanol. The MoVI atom is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate 1-[(2-oxidopropyl)iminomethyl]-2-naphtholate Schiff base ligand. The coordination sphere is completed by the O atom of a methanol molecule, yielding a distorted octahedron. O—H...O hydrogen bonding yields centrosymmetric dimers. |
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| ISSN: | 1600-5368 |