(Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)zinc perchlorate
The ZnII atom in the cation of the title salt, [Zn(C2H3O2)(C18H40N4)]ClO4, is five-coordinated by the four N atoms of the macrocycle and the O atom of the monodentate acetate ligand. The N4O donor set is based on a trigonal bipyramid with two N atoms occupying axial positions [N—Zn&...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811045582 |
| id |
doaj-59f7b2318a944a52bdf6e2d888371fe8 |
|---|---|
| record_format |
Article |
| spelling |
doaj-59f7b2318a944a52bdf6e2d888371fe82020-11-25T01:56:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1659m166010.1107/S1600536811045582(Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)zinc perchlorateTapashi G. RoySaroj K. S. HazariKanak K. BaruaEdward R. T. TiekinkThe ZnII atom in the cation of the title salt, [Zn(C2H3O2)(C18H40N4)]ClO4, is five-coordinated by the four N atoms of the macrocycle and the O atom of the monodentate acetate ligand. The N4O donor set is based on a trigonal bipyramid with two N atoms occupying axial positions [N—Zn—N = 170.89 (16)°]. The perchlorate anions are associated with the cations via N—H...O hydrogen bonds; intramolecular N—H...O(acetate) interactions are also observed. The neutral aggregates are connected into an helical chain along the b axis via N—H...O(acetate) hydrogen bonds. The perchlorate anion was found to be disordered about a pseudo-threefold axis: the major component of the disorder had a site occupancy factor of 0.692 (11).http://scripts.iucr.org/cgi-bin/paper?S1600536811045582 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Tapashi G. Roy Saroj K. S. Hazari Kanak K. Barua Edward R. T. Tiekink |
| spellingShingle |
Tapashi G. Roy Saroj K. S. Hazari Kanak K. Barua Edward R. T. Tiekink (Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)zinc perchlorate Acta Crystallographica Section E |
| author_facet |
Tapashi G. Roy Saroj K. S. Hazari Kanak K. Barua Edward R. T. Tiekink |
| author_sort |
Tapashi G. Roy |
| title |
(Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)zinc perchlorate |
| title_short |
(Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)zinc perchlorate |
| title_full |
(Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)zinc perchlorate |
| title_fullStr |
(Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)zinc perchlorate |
| title_full_unstemmed |
(Acetato-κO)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)zinc perchlorate |
| title_sort |
(acetato-κo)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4n,n′,n′′,n′′′)zinc perchlorate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-12-01 |
| description |
The ZnII atom in the cation of the title salt, [Zn(C2H3O2)(C18H40N4)]ClO4, is five-coordinated by the four N atoms of the macrocycle and the O atom of the monodentate acetate ligand. The N4O donor set is based on a trigonal bipyramid with two N atoms occupying axial positions [N—Zn—N = 170.89 (16)°]. The perchlorate anions are associated with the cations via N—H...O hydrogen bonds; intramolecular N—H...O(acetate) interactions are also observed. The neutral aggregates are connected into an helical chain along the b axis via N—H...O(acetate) hydrogen bonds. The perchlorate anion was found to be disordered about a pseudo-threefold axis: the major component of the disorder had a site occupancy factor of 0.692 (11). |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811045582 |
| work_keys_str_mv |
AT tapashigroy acetatoamp954o25579121214octamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242zincperchlorate AT sarojkshazari acetatoamp954o25579121214octamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242zincperchlorate AT kanakkbarua acetatoamp954o25579121214octamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242zincperchlorate AT edwardrttiekink acetatoamp954o25579121214octamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242zincperchlorate |
| _version_ |
1724978801539022848 |