Bis(tetraethylammonium) oxalate dihydrate

Bis(tetraethylammonium) oxalate dihydrate

The title compound, 2C8H20N+·C2O42−·2H2O, synthesized by neutralizing H2C2O4·2H2O with (C2H5)4NOH in a 1:2 molar ratio, is a deliquescent solid. The oxalate ion is nonplanar, with a dihedral angle between carboxylate groups of 64.37 ...

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Main Authors: Timothy J. McNeese, Robert D. Pike
Format: Article
Language:English
Published: International Union of Crystallography 2012-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681203022X
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spelling doaj-59acb3246e7f45cd9c7b3c437d6562fe2020-11-25T02:46:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688o2382o238310.1107/S160053681203022XBis(tetraethylammonium) oxalate dihydrateTimothy J. McNeeseRobert D. PikeThe title compound, 2C8H20N+·C2O42−·2H2O, synthesized by neutralizing H2C2O4·2H2O with (C2H5)4NOH in a 1:2 molar ratio, is a deliquescent solid. The oxalate ion is nonplanar, with a dihedral angle between carboxylate groups of 64.37 (2)°. O—H...O hydrogen bonds of moderate strength link the O atoms of the water molecules and the oxalate ions into rings parallel to the c axis. The rings exhibit the graph-set motif R44(12). In addition, there are weak C—H...O interactions in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S160053681203022X
collection DOAJ
language English
format Article
sources DOAJ
author Timothy J. McNeese
Robert D. Pike
spellingShingle Timothy J. McNeese
Robert D. Pike
Bis(tetraethylammonium) oxalate dihydrate
Acta Crystallographica Section E
author_facet Timothy J. McNeese
Robert D. Pike
author_sort Timothy J. McNeese
title Bis(tetraethylammonium) oxalate dihydrate
title_short Bis(tetraethylammonium) oxalate dihydrate
title_full Bis(tetraethylammonium) oxalate dihydrate
title_fullStr Bis(tetraethylammonium) oxalate dihydrate
title_full_unstemmed Bis(tetraethylammonium) oxalate dihydrate
title_sort bis(tetraethylammonium) oxalate dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-08-01
description The title compound, 2C8H20N+·C2O42−·2H2O, synthesized by neutralizing H2C2O4·2H2O with (C2H5)4NOH in a 1:2 molar ratio, is a deliquescent solid. The oxalate ion is nonplanar, with a dihedral angle between carboxylate groups of 64.37 (2)°. O—H...O hydrogen bonds of moderate strength link the O atoms of the water molecules and the oxalate ions into rings parallel to the c axis. The rings exhibit the graph-set motif R44(12). In addition, there are weak C—H...O interactions in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S160053681203022X
work_keys_str_mv AT timothyjmcneese bistetraethylammoniumoxalatedihydrate
AT robertdpike bistetraethylammoniumoxalatedihydrate
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