[3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid

[3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid

In the title compound, C13H11BBrFO3, the dioxyboron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH g...

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Main Authors: Kinga Kacprzak, Tomasz Klis, Janusz Serwatowski
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809033376
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spelling doaj-599eb20436994566a211600dbd7fe09a2020-11-24T21:26:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659o2250o225010.1107/S1600536809033376[3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acidKinga KacprzakTomasz KlisJanusz SerwatowskiIn the title compound, C13H11BBrFO3, the dioxyboron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intramolecular O—H...O hydrogen-bonding interaction. The second OH group is involved in intermolecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio. http://scripts.iucr.org/cgi-bin/paper?S1600536809033376
collection DOAJ
language English
format Article
sources DOAJ
author Kinga Kacprzak
Tomasz Klis
Janusz Serwatowski
spellingShingle Kinga Kacprzak
Tomasz Klis
Janusz Serwatowski
[3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
Acta Crystallographica Section E
author_facet Kinga Kacprzak
Tomasz Klis
Janusz Serwatowski
author_sort Kinga Kacprzak
title [3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
title_short [3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
title_full [3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
title_fullStr [3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
title_full_unstemmed [3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
title_sort [3-bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description In the title compound, C13H11BBrFO3, the dioxyboron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intramolecular O—H...O hydrogen-bonding interaction. The second OH group is involved in intermolecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809033376
work_keys_str_mv AT kingakacprzak 3bromo23fluorobenzyloxyphenylboronicacid
AT tomaszklis 3bromo23fluorobenzyloxyphenylboronicacid
AT januszserwatowski 3bromo23fluorobenzyloxyphenylboronicacid
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