[3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
In the title compound, C13H11BBrFO3, the dioxyboron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH g...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809033376 |
| Summary: | In the title compound, C13H11BBrFO3, the dioxyboron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intramolecular O—H...O hydrogen-bonding interaction. The second OH group is involved in intermolecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio. |
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| ISSN: | 1600-5368 |