catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]

catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]

Cobalt(II) nitrate hexahydrate and sodium dicyanamide self-assembled in dimethylformamide (DMF) and 4-methylpyridine solutions to form the title compound, [Co(C2N3)2(C6H7N)2]n. The Co2+ ion lies on an inversion center and adopts an octahedral coordination geometry in which four N atoms from four dif...

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Main Authors: Wenjiang Huang, Jinfang Zhang, Chi Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2013-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812051252
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spelling doaj-5965cc1f749e4a8e9c51d5fc96ebebb52020-11-25T01:33:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-02-01692m90m9010.1107/S1600536812051252catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]Wenjiang HuangJinfang ZhangChi ZhangCobalt(II) nitrate hexahydrate and sodium dicyanamide self-assembled in dimethylformamide (DMF) and 4-methylpyridine solutions to form the title compound, [Co(C2N3)2(C6H7N)2]n. The Co2+ ion lies on an inversion center and adopts an octahedral coordination geometry in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two 4-methylpyridine N atoms occupy the axial positions. The CoII atoms are connected by two bridging dicyanamide ligands, resulting in a chain parallel to the c axis. The chains are connected into a three-dimensional network by C—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812051252
collection DOAJ
language English
format Article
sources DOAJ
author Wenjiang Huang
Jinfang Zhang
Chi Zhang
spellingShingle Wenjiang Huang
Jinfang Zhang
Chi Zhang
catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]
Acta Crystallographica Section E
author_facet Wenjiang Huang
Jinfang Zhang
Chi Zhang
author_sort Wenjiang Huang
title catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]
title_short catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]
title_full catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]
title_fullStr catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]
title_full_unstemmed catena-Poly[[bis(4-methylpyridine-κN)cobalt(II)]-di-μ-dicyanamido-κ2N1:N5]
title_sort catena-poly[[bis(4-methylpyridine-κn)cobalt(ii)]-di-μ-dicyanamido-κ2n1:n5]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-02-01
description Cobalt(II) nitrate hexahydrate and sodium dicyanamide self-assembled in dimethylformamide (DMF) and 4-methylpyridine solutions to form the title compound, [Co(C2N3)2(C6H7N)2]n. The Co2+ ion lies on an inversion center and adopts an octahedral coordination geometry in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two 4-methylpyridine N atoms occupy the axial positions. The CoII atoms are connected by two bridging dicyanamide ligands, resulting in a chain parallel to the c axis. The chains are connected into a three-dimensional network by C—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812051252
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AT jinfangzhang catenapolybis4methylpyridine954ncobaltiidi956dicyanamido9542n1n5
AT chizhang catenapolybis4methylpyridine954ncobaltiidi956dicyanamido9542n1n5
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