Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]

Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]

In the structure of the title coordination polymer, [K(C8H5N2O6)]n, each ligand bridges six K+ cations. The carboxylate group coordinates both bidentately to one K+ ion and monodentately to two K+ ions, while one nitro group coordinates bidentately to a fourth K+ ion. The last two K+ ions are coordi...

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Main Authors: Muhammad Danish, Iram Saleem, Nazir Ahmad, Wojciech Starosta, Janusz Leciejewicz
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810015400
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spelling doaj-595778aaf36d43458b662f1dea21a4552020-11-25T00:49:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m616m61610.1107/S1600536810015400Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]Muhammad DanishIram SaleemNazir AhmadWojciech StarostaJanusz LeciejewiczIn the structure of the title coordination polymer, [K(C8H5N2O6)]n, each ligand bridges six K+ cations. The carboxylate group coordinates both bidentately to one K+ ion and monodentately to two K+ ions, while one nitro group coordinates bidentately to a fourth K+ ion. The last two K+ ions are coordinated by the remaining nitro group, one in a bidentate fashion, the other monodentately through one O atom. This bridging mode results in a three-dimensional network. The coordination geometry of the K+ ion is represented by an irregular KO9 polyhedron. Very weak C—H...O interactions are observed in the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810015400
collection DOAJ
language English
format Article
sources DOAJ
author Muhammad Danish
Iram Saleem
Nazir Ahmad
Wojciech Starosta
Janusz Leciejewicz
spellingShingle Muhammad Danish
Iram Saleem
Nazir Ahmad
Wojciech Starosta
Janusz Leciejewicz
Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]
Acta Crystallographica Section E
author_facet Muhammad Danish
Iram Saleem
Nazir Ahmad
Wojciech Starosta
Janusz Leciejewicz
author_sort Muhammad Danish
title Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]
title_short Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]
title_full Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]
title_fullStr Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]
title_full_unstemmed Poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]
title_sort poly[(μ6-2-methyl-3,5-dinitrobenzoato)potassium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-06-01
description In the structure of the title coordination polymer, [K(C8H5N2O6)]n, each ligand bridges six K+ cations. The carboxylate group coordinates both bidentately to one K+ ion and monodentately to two K+ ions, while one nitro group coordinates bidentately to a fourth K+ ion. The last two K+ ions are coordinated by the remaining nitro group, one in a bidentate fashion, the other monodentately through one O atom. This bridging mode results in a three-dimensional network. The coordination geometry of the K+ ion is represented by an irregular KO9 polyhedron. Very weak C—H...O interactions are observed in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810015400
work_keys_str_mv AT muhammaddanish polyamp95662methyl35dinitrobenzoatopotassium
AT iramsaleem polyamp95662methyl35dinitrobenzoatopotassium
AT nazirahmad polyamp95662methyl35dinitrobenzoatopotassium
AT wojciechstarosta polyamp95662methyl35dinitrobenzoatopotassium
AT januszleciejewicz polyamp95662methyl35dinitrobenzoatopotassium
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