A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure

A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure

A novel tetranuclear silver coordination compound with the formula [Ag4(bdmpza)4]×10H2O (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate) was synthesized by a reaction between an aqueous solution of silver nitrate and an aqueous solution prepared by bis(3,5-dimethylpyrazol-1-yl)acetic acid and potassi...

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Bibliographic Details
Main Authors: Marta Počkaj, Nives Kitanovski
Format: Article
Language:English
Published: Slovenian Chemical Society 2021-09-01
Series:Acta Chimica Slovenica
Subjects:
coordination chemistry
silver, bis(3,5-dimethylpyrazol -1-yl)acetate
crystal structure
hirshfeld surface analysis
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/6961
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spelling doaj-592573fdc7974fc18b1d75a9a063412a2021-09-30T07:59:01ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552021-09-0168353254010.17344/acsi.2021.69611005A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal StructureMarta Počkaj0Nives Kitanovski1Faculty of Chemistry and Chemical Technology, University of Ljubljana Večna pot 113, SI-1000 Ljubljana, SloveniaFaculty of Chemistry and Chemical Technology, University of Ljubljana Večna pot 113, SI-1000 Ljubljana, SloveniaA novel tetranuclear silver coordination compound with the formula [Ag4(bdmpza)4]×10H2O (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate) was synthesized by a reaction between an aqueous solution of silver nitrate and an aqueous solution prepared by bis(3,5-dimethylpyrazol-1-yl)acetic acid and potassium  hydroxide (1:1 molar ratio). The obtained compound was characterized by elemental analysis, coupled thermogravimetric–mass spectrometry analysis, vibrational IR spectroscopy, and its crystal structure was determined by single-crystal X-ray diffraction method. Furthermore, the obtained crystal structure was additionally evaluated by Hirshfeld surface analysis.https://journals.matheo.si/index.php/ACSi/article/view/6961coordination chemistrysilver, bis(3,5-dimethylpyrazol -1-yl)acetatecrystal structurehirshfeld surface analysis
collection DOAJ
language English
format Article
sources DOAJ
author Marta Počkaj
Nives Kitanovski
spellingShingle Marta Počkaj
Nives Kitanovski
A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure
Acta Chimica Slovenica
coordination chemistry
silver, bis(3,5-dimethylpyrazol -1-yl)acetate
crystal structure
hirshfeld surface analysis
author_facet Marta Počkaj
Nives Kitanovski
author_sort Marta Počkaj
title A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure
title_short A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure
title_full A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure
title_fullStr A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure
title_full_unstemmed A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure
title_sort novel tetranuclear silver compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a simple synthesis yielding complex crystal structure
publisher Slovenian Chemical Society
series Acta Chimica Slovenica
issn 1318-0207
1580-3155
publishDate 2021-09-01
description A novel tetranuclear silver coordination compound with the formula [Ag4(bdmpza)4]×10H2O (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate) was synthesized by a reaction between an aqueous solution of silver nitrate and an aqueous solution prepared by bis(3,5-dimethylpyrazol-1-yl)acetic acid and potassium  hydroxide (1:1 molar ratio). The obtained compound was characterized by elemental analysis, coupled thermogravimetric–mass spectrometry analysis, vibrational IR spectroscopy, and its crystal structure was determined by single-crystal X-ray diffraction method. Furthermore, the obtained crystal structure was additionally evaluated by Hirshfeld surface analysis.
topic coordination chemistry
silver, bis(3,5-dimethylpyrazol -1-yl)acetate
crystal structure
hirshfeld surface analysis
url https://journals.matheo.si/index.php/ACSi/article/view/6961
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AT niveskitanovski anoveltetranuclearsilvercompoundwithbis35dimethylpyrazol1ylacetateasimplesynthesisyieldingcomplexcrystalstructure
AT martapockaj noveltetranuclearsilvercompoundwithbis35dimethylpyrazol1ylacetateasimplesynthesisyieldingcomplexcrystalstructure
AT niveskitanovski noveltetranuclearsilvercompoundwithbis35dimethylpyrazol1ylacetateasimplesynthesisyieldingcomplexcrystalstructure
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