A Mathematical Model of the Single Aluminium Diboride Particle Ignition

• Main Authors: D. A. Yagodnikov, P. V. Papirin, A. V. Sukhov
• Format: Article
• Language: Russian
• Published: MGTU im. N.È. Baumana 2014-01-01
• Series: Nauka i Obrazovanie
• Subjects: aluminum diborid; single particle; ignition; parallel reactions; ignition time
• Online Access: http://technomag.edu.ru/jour/article/view/844

<p>The paper presents a developed mathematical model of ignition of the single aluminum diboride particle as an aluminum-boron alloy in the oxidizing environment of a complicated chemical composition containing oxygen, water vapor, and carbon dioxide. The mathematical model is based on the theory of parallel chemical reactions proceeding on the appropriate parts of the particle surface occupied by each element in proportion to their molar share in the alloy. The paper considers a possibility to establish a thermodynamic balance between components over a particle surface in the gas phase. The composition of components is chosen as a result of thermodynamic calculation, namely В g , B2O3 g , BO, B2O2, BO2, Alg , AlO, Al2O, N2. The mathematical model is formed by a system of the differential equations of enthalpy balance, mass of aluminum diboride particle, and of formed oxides, which become isolated by initial and boundary conditions for temperature and size of particles, concentration of an oxidizer, and temperature of gas. The software package “AlB2“ is developed. It is a complete independent module written in Fortran algorithmic language, which together with a package of the subroutines “SPARKS” is used to calculate parameters of burning aluminum diboride particle by the Runge-Kutt method.</p><p>For stoichiometry of chemical reactions of interaction between aluminum diboride and oxygen, a dynamics of changing temperature of a particle and thickness of an oxide film on its surface is calculated. It was admitted as initial conditions that the aluminum diboride particle radius was 100μ and the reference temperature of environment was 500 K, 1000 K, 2300 K, and 3000 K. Depending on this temperature the aluminum diboride particle temperature was calculated. Changing thickness of the oxide film on the particle surface at various initial gas temperatures characterizes its increase at the initial heating period of ~ 0,01 s and a gradual slowdown of the oxidation process caused by increasing protective properties of the oxide film. It is shown that the condition of the thermal balance failure can be accepted as a criterion of ignition. Accordingly, the total heat emission of the particle at the moment of ignition resulted from the chemical reactions has to exceed heat losses on the particle.</p>