Crystal structure and redox potentials of the tppz-bridged {RuCl(bpy)}+ dimer

Crystal structure and redox potentials of the tppz-bridged {RuCl(bpy)}+ dimer

We report the structural and electrochemical characterization of the binuclear complex [μ-(C24H16N6){RuCl(C10H8N2)}2](PF6)2, which contains the bis-tridentate bridging ligand 2,3,5,6-tetrakis(pyridin-2-yl)pyrazine (tppz), the monodentate ligand Cl−, and the bidentate ligand 2,2′-bipyridine (bpy) {sy...

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Bibliographic Details
Main Authors: Francisca N. Rein, Weizhong Chen, Brian L. Scott, Reginaldo C. Rocha
Format: Article
Language:English
Published: International Union of Crystallography 2018-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
dinuclear complex
electrochemistry
tetra(pyridyl)pyrazine
ruthenium precatalyst
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018011258

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http://scripts.iucr.org/cgi-bin/paper?S2056989018011258

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