Tribological and nanomechanical properties of a lignin-based biopolymer

• Main Authors: Broitman Esteban, Nedelcu Dumitru, Mazurchevici Simona-Nicoleta
• Format: Article
• Language: English
• Published: De Gruyter 2020-09-01
• Series: e-Polymers
• Subjects: biopolymers; lignin; arboblend v2 nature; nanoindentation; wear; friction
• Online Access: http://www.degruyter.com/view/j/epoly.2020.20.issue-1/epoly-2020-0055/epoly-2020-0055.xml?format=INT

A research is reported on the nanomechanics and tribology of the Arboblend V2 Nature biopolymer (a 100% bio-based material, biodegradable, or resistant depending of application), being a mixture of different biopolymers such as lignin, polylactic acid, cellulose, biopolyamides, and other natural additives. The specimens were made by an industrial-scale injection molding machine. The nanoindentation characterization have unveiled that an increase in processing temperature from 160°C to 170°C produces a rise in hardness and elastic modulus of ∼20%. Tribological characterization against a bearing-steel counterface has shown that for both processing temperatures, the increase of the applied load or the increase of sliding speed will produce an increase of the friction coefficient (µ) and wear. At an applied load of 1 N (contact pressure of 104 MPa) and tracks in a direction perpendicular to the surface textured lines, the lowest µ ∼ 0.148 are for samples made T = 170°C, while for tracks parallel to the textured lines, the lowest µ ∼ 0.059 is obtained for samples made at T = 160°C. Experiments made at different ambient humidity have established that friction coefficient is higher at 0% RH or at 75% RH than at 33% RH. Our results show that the biopolymers Arboblend V2 Nature is a candidate to substitute some popular fossil-based thermoplastics in numerous tribological industrial applications.