(Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one

The title compound, C23H16N2O3, exists in a Z configuration with respect to the acyclic C=C bond. The pyridine and phenyl rings are oriented at dihedral angles of 72.97 (4) and 45.05 (4)°, respectively, with respect to the almost planar indoline ring system [...

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Bibliographic Details
Main Authors: Hoong-Kun Fun, Jia Hao Goh, Haitao Yu, Yan Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810030874
Description
Summary:The title compound, C23H16N2O3, exists in a Z configuration with respect to the acyclic C=C bond. The pyridine and phenyl rings are oriented at dihedral angles of 72.97 (4) and 45.05 (4)°, respectively, with respect to the almost planar indoline ring system [maximum deviation 0.080 (1) Å]. The pyridine and phenyl rings are oriented almost perpendicular to each other [dihedral angle 88.93 (5)°]. In the crystal, molecules are interconnected into a three-dimensional framework via intermolecular C—H...O and C—H...N hydrogen bonds and weak π–π interactions [centroid–centroid distance = 3.681 (1) Å].
ISSN:1600-5368