(N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)

(N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)

The title organometallic complex, [Bi(C6H5)(C6H4NO3)2(C3H7NO)], features a BiIII atom in a distorted pentagonal-pyramidal coordination by two N,O-donating bidentate 3-hydroxypicolinate (3-hpic) ligands, one monodentate dimethylformamide (dmf) molecule and one phenyl ring. The C atom of the aryl liga...

Full description

Bibliographic Details
Main Authors: Vitalie Stavila, Kenton H. Whitmire
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810044235
id doaj-56fd6598eaa14daea19c8f751fdb1c05
record_format Article
spelling doaj-56fd6598eaa14daea19c8f751fdb1c052020-11-24T20:48:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1547m154810.1107/S1600536810044235(N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)Vitalie StavilaKenton H. WhitmireThe title organometallic complex, [Bi(C6H5)(C6H4NO3)2(C3H7NO)], features a BiIII atom in a distorted pentagonal-pyramidal coordination by two N,O-donating bidentate 3-hydroxypicolinate (3-hpic) ligands, one monodentate dimethylformamide (dmf) molecule and one phenyl ring. The C atom of the aryl ligand occupies the apical position of the BiCN2O3 coordination polyhedron, while the equatorial plane is formed by one O atom of the dmf ligand and two sets of N and O atoms from the chelating 3-hpic ligands. Intermolecular secondary Bi...O [3.485 (3) Å] and O—H...O hydrogen-bonding interactions connect the complexes into a three-dimensional network. Intramolecular O—H...O hydrogen bonds are also observed. http://scripts.iucr.org/cgi-bin/paper?S1600536810044235
collection DOAJ
language English
format Article
sources DOAJ
author Vitalie Stavila
Kenton H. Whitmire
spellingShingle Vitalie Stavila
Kenton H. Whitmire
(N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)
Acta Crystallographica Section E
author_facet Vitalie Stavila
Kenton H. Whitmire
author_sort Vitalie Stavila
title (N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)
title_short (N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)
title_full (N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)
title_fullStr (N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)
title_full_unstemmed (N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2)phenylbismuth(III)
title_sort (n,n-dimethylformamide-κo)bis(3-hydroxypicolinato-κ2n,o2)phenylbismuth(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description The title organometallic complex, [Bi(C6H5)(C6H4NO3)2(C3H7NO)], features a BiIII atom in a distorted pentagonal-pyramidal coordination by two N,O-donating bidentate 3-hydroxypicolinate (3-hpic) ligands, one monodentate dimethylformamide (dmf) molecule and one phenyl ring. The C atom of the aryl ligand occupies the apical position of the BiCN2O3 coordination polyhedron, while the equatorial plane is formed by one O atom of the dmf ligand and two sets of N and O atoms from the chelating 3-hpic ligands. Intermolecular secondary Bi...O [3.485 (3) Å] and O—H...O hydrogen-bonding interactions connect the complexes into a three-dimensional network. Intramolecular O—H...O hydrogen bonds are also observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810044235
work_keys_str_mv AT vitaliestavila nndimethylformamideamp954obis3hydroxypicolinatoamp9542no2phenylbismuthiii
AT kentonhwhitmire nndimethylformamideamp954obis3hydroxypicolinatoamp9542no2phenylbismuthiii
_version_ 1716807528670560256

Similar Items