Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn(II) With Amide Containing Ligands
The present research work describes the synthesis, spectral and antibacterial studies on the complexes of Mn(II) with amide group containing ligands. Synthesis of complexes has been carried out by conventional method as well as by microwave method. The complexes have been characterized on the basis...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Hindawi Limited
2007-01-01
|
Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2007/785626 |
id |
doaj-56f374a9afbf454daf4ca0e490f47585 |
---|---|
record_format |
Article |
spelling |
doaj-56f374a9afbf454daf4ca0e490f475852020-11-24T22:08:12ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102007-01-014223223710.1155/2007/785626Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn(II) With Amide Containing LigandsN. Bhojak0D. D. Gudasaria1N. Khiwani2R. Jain3Green Chemistry Research Centre, P.G. Department of Chemistry, Govt. Dungar College (A-Grade), University of Bikaner, Bikaner-334003, IndiaGreen Chemistry Research Centre, P.G. Department of Chemistry, Govt. Dungar College (A-Grade), University of Bikaner, Bikaner-334003, IndiaGreen Chemistry Research Centre, P.G. Department of Chemistry, Govt. Dungar College (A-Grade), University of Bikaner, Bikaner-334003, IndiaGreen Chemistry Research Centre, P.G. Department of Chemistry, Govt. Dungar College (A-Grade), University of Bikaner, Bikaner-334003, IndiaThe present research work describes the synthesis, spectral and antibacterial studies on the complexes of Mn(II) with amide group containing ligands. Synthesis of complexes has been carried out by conventional method as well as by microwave method. The complexes have been characterized on the basis of elemental analysis, infrared, electronic spectra and magnetic susceptibility studies. The diffuse reflectance spectrums of the complexes show bands in the region 20,000 cm-1 to 26,000 cm-1 assignable to 6A1g → 4T2g and 6A1g → 4E1g transitions. These are also typical of tetrahedral environment around the manganese. The magnetic moment (5.80 BM) of the complex indicates high spin tetrahedral environment. The microwave method of synthesis of complexes have been found easier, convenient and ecofriendly.http://dx.doi.org/10.1155/2007/785626 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
N. Bhojak D. D. Gudasaria N. Khiwani R. Jain |
spellingShingle |
N. Bhojak D. D. Gudasaria N. Khiwani R. Jain Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn(II) With Amide Containing Ligands E-Journal of Chemistry |
author_facet |
N. Bhojak D. D. Gudasaria N. Khiwani R. Jain |
author_sort |
N. Bhojak |
title |
Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn(II) With Amide Containing Ligands |
title_short |
Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn(II) With Amide Containing Ligands |
title_full |
Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn(II) With Amide Containing Ligands |
title_fullStr |
Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn(II) With Amide Containing Ligands |
title_full_unstemmed |
Microwave Assisted Synthesis Spectral and Antibacterial Investigations on Complexes of Mn(II) With Amide Containing Ligands |
title_sort |
microwave assisted synthesis spectral and antibacterial investigations on complexes of mn(ii) with amide containing ligands |
publisher |
Hindawi Limited |
series |
E-Journal of Chemistry |
issn |
0973-4945 2090-9810 |
publishDate |
2007-01-01 |
description |
The present research work describes the synthesis, spectral and antibacterial studies on the complexes of Mn(II) with amide group containing ligands. Synthesis of complexes has been carried out by conventional method as well as by microwave method. The complexes have been characterized on the basis of elemental analysis, infrared, electronic spectra and magnetic susceptibility studies. The diffuse reflectance spectrums of the complexes show bands in the region 20,000 cm-1 to 26,000 cm-1 assignable to 6A1g → 4T2g and 6A1g → 4E1g transitions. These are also typical of tetrahedral environment around the manganese. The magnetic moment (5.80 BM) of the complex indicates high spin tetrahedral environment. The microwave method of synthesis of complexes have been found easier, convenient and ecofriendly. |
url |
http://dx.doi.org/10.1155/2007/785626 |
work_keys_str_mv |
AT nbhojak microwaveassistedsynthesisspectralandantibacterialinvestigationsoncomplexesofmniiwithamidecontainingligands AT ddgudasaria microwaveassistedsynthesisspectralandantibacterialinvestigationsoncomplexesofmniiwithamidecontainingligands AT nkhiwani microwaveassistedsynthesisspectralandantibacterialinvestigationsoncomplexesofmniiwithamidecontainingligands AT rjain microwaveassistedsynthesisspectralandantibacterialinvestigationsoncomplexesofmniiwithamidecontainingligands |
_version_ |
1725817263060156416 |