Nonmonotonic (in concentration) conductivity of aqueous solutions of fungal melanin

The conductivity of aqueous (distilled and natural water) solutions of fungal melanin (purified and non-purified) has been studied. It has been shown that, in the presence of impurities, the conductivity of solution increases (for the concentration 0.1 wt% about an order of magnitude). On the concen...

Full description

Bibliographic Details
Main Authors: O.V. Kovalchuk, T.M. Kovalchuk
Format: Article
Language:English
Published: National Academy of Sciences of Ukraine. Institute of Semi conductor physics. 2018-03-01
Series:Semiconductor Physics, Quantum Electronics & Optoelectronics
Subjects:
Online Access:http://journal-spqeo.org.ua/n1_2018/P095-099abstr.html
Description
Summary:The conductivity of aqueous (distilled and natural water) solutions of fungal melanin (purified and non-purified) has been studied. It has been shown that, in the presence of impurities, the conductivity of solution increases (for the concentration 0.1 wt% about an order of magnitude). On the concentration dependences of the melanin conductivity within the range of 0.0001 to 1 wt.% at least three particular sections have been detected. It was suggested that the presence of such sections is caused by three types of aggregation of melanin molecules: aggregation of several (mostly oppositely charged) molecules under the lowest melanin concentration, formation of nanoscale melanin clusters for the concentration of 0.002 to 0.06 wt.% and formation of micelles, when the melanin concentration is higher than 0.1 wt.%.
ISSN:1560-8034
1605-6582