Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen Tartrate

Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen Tartrate

Organic nonlinear optical crystal morpholinium hydrogen tartrate (MHT), with molecular formula [C8H15NO7], has been grown by slow evaporation solution technique. Single crystal X-ray diffraction study confirms that MHT crystallizes in orthorhombic system with noncentrosymmetric space group P212121....

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Main Authors: R. Renugadevi, R. Kesavasamy
Format: Article
Language:English
Published: Hindawi Limited 2014-01-01
Series:Advances in Condensed Matter Physics
Online Access:http://dx.doi.org/10.1155/2014/834760
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spelling doaj-56146d4264384d4c899d0938bb6c2aab2020-11-24T21:32:07ZengHindawi LimitedAdvances in Condensed Matter Physics1687-81081687-81242014-01-01201410.1155/2014/834760834760Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen TartrateR. Renugadevi0R. Kesavasamy1Department of Physics, SriGuru Institute of Technology, Coimbatore,Tamilnadu 641 110, IndiaDepartment of Physics, Sri Ramakrishna Engineering College, Coimbatore,Tamilnadu 641 020, IndiaOrganic nonlinear optical crystal morpholinium hydrogen tartrate (MHT), with molecular formula [C8H15NO7], has been grown by slow evaporation solution technique. Single crystal X-ray diffraction study confirms that MHT crystallizes in orthorhombic system with noncentrosymmetric space group P212121. FTIR spectrum was recorded to identify the various functional groups of MHT. The various kinds of protons and carbons of MHT have been identified using 1H and 13C NMR spectral analyses. The range of optical absorption was ascertained by recording UV-Vis-NIR spectral studies. The TG/DTA studies revealed that the grown crystal is thermally stable up to 159.26°C. The mechanical property of the grown crystal was studied using Vickers microhardness studies. The relative second harmonic generation efficiency of MHT was determined using Kurtz and Perry powder technique; it was observed to be greater than that of KDP crystal.http://dx.doi.org/10.1155/2014/834760
collection DOAJ
language English
format Article
sources DOAJ
author R. Renugadevi
R. Kesavasamy
spellingShingle R. Renugadevi
R. Kesavasamy
Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen Tartrate
Advances in Condensed Matter Physics
author_facet R. Renugadevi
R. Kesavasamy
author_sort R. Renugadevi
title Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen Tartrate
title_short Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen Tartrate
title_full Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen Tartrate
title_fullStr Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen Tartrate
title_full_unstemmed Investigation on Growth, Structural, Spectral, Optical, and Mechanical Properties of an Organic Nonlinear Optical Material: Morpholinium Hydrogen Tartrate
title_sort investigation on growth, structural, spectral, optical, and mechanical properties of an organic nonlinear optical material: morpholinium hydrogen tartrate
publisher Hindawi Limited
series Advances in Condensed Matter Physics
issn 1687-8108
1687-8124
publishDate 2014-01-01
description Organic nonlinear optical crystal morpholinium hydrogen tartrate (MHT), with molecular formula [C8H15NO7], has been grown by slow evaporation solution technique. Single crystal X-ray diffraction study confirms that MHT crystallizes in orthorhombic system with noncentrosymmetric space group P212121. FTIR spectrum was recorded to identify the various functional groups of MHT. The various kinds of protons and carbons of MHT have been identified using 1H and 13C NMR spectral analyses. The range of optical absorption was ascertained by recording UV-Vis-NIR spectral studies. The TG/DTA studies revealed that the grown crystal is thermally stable up to 159.26°C. The mechanical property of the grown crystal was studied using Vickers microhardness studies. The relative second harmonic generation efficiency of MHT was determined using Kurtz and Perry powder technique; it was observed to be greater than that of KDP crystal.
url http://dx.doi.org/10.1155/2014/834760
work_keys_str_mv AT rrenugadevi investigationongrowthstructuralspectralopticalandmechanicalpropertiesofanorganicnonlinearopticalmaterialmorpholiniumhydrogentartrate
AT rkesavasamy investigationongrowthstructuralspectralopticalandmechanicalpropertiesofanorganicnonlinearopticalmaterialmorpholiniumhydrogentartrate
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