Zn1.86Cd0.14(OH)VO4

Zn1.86Cd0.14(OH)VO4

The title compound, dizinc cadmium hydroxide tetraoxidovanadate, Zn1.86Cd0.14(OH)VO4, was prepared under low-temperature hydrothermal conditions. It is isostructural with Zn2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are interconnected by VO4 tetrahedra...

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Main Authors: Tamara Đorđević, Ljiljana Karanović, Jovica Stojanović
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810044806
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spelling doaj-55fcfdbdd0de40d2bc6f18425944006e2020-11-25T01:13:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612i79i7910.1107/S1600536810044806Zn1.86Cd0.14(OH)VO4Tamara ĐorđevićLjiljana KaranovićJovica StojanovićThe title compound, dizinc cadmium hydroxide tetraoxidovanadate, Zn1.86Cd0.14(OH)VO4, was prepared under low-temperature hydrothermal conditions. It is isostructural with Zn2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are interconnected by VO4 tetrahedra (site symmetries of both V atoms and their coordination polyhedra are .m.) to form a three-dimensional [Zn(OH)VO4]2− framework with channels occupied by Zn and Zn/Cd cations adopting trigonal–bipyramidal and distorted octahedral coordinations, respectively. Zn1.86Cd0.14(OH)VO4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures. http://scripts.iucr.org/cgi-bin/paper?S1600536810044806
collection DOAJ
language English
format Article
sources DOAJ
author Tamara Đorđević
Ljiljana Karanović
Jovica Stojanović
spellingShingle Tamara Đorđević
Ljiljana Karanović
Jovica Stojanović
Zn1.86Cd0.14(OH)VO4
Acta Crystallographica Section E
author_facet Tamara Đorđević
Ljiljana Karanović
Jovica Stojanović
author_sort Tamara Đorđević
title Zn1.86Cd0.14(OH)VO4
title_short Zn1.86Cd0.14(OH)VO4
title_full Zn1.86Cd0.14(OH)VO4
title_fullStr Zn1.86Cd0.14(OH)VO4
title_full_unstemmed Zn1.86Cd0.14(OH)VO4
title_sort zn1.86cd0.14(oh)vo4
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description The title compound, dizinc cadmium hydroxide tetraoxidovanadate, Zn1.86Cd0.14(OH)VO4, was prepared under low-temperature hydrothermal conditions. It is isostructural with Zn2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are interconnected by VO4 tetrahedra (site symmetries of both V atoms and their coordination polyhedra are .m.) to form a three-dimensional [Zn(OH)VO4]2− framework with channels occupied by Zn and Zn/Cd cations adopting trigonal–bipyramidal and distorted octahedral coordinations, respectively. Zn1.86Cd0.14(OH)VO4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810044806
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AT ljiljanakaranoviamp263 zn186cd014ohvo4
AT jovicastojanoviamp263 zn186cd014ohvo4
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