O emprego da termogravimetria para determinar a energia de ativação do processo de combustão de óleos combustíveis

• Main Authors: Cecilia Rocío Morales Leiva, Paula Manoel Crnkovic, Antonio Moreira dos Santos
• Format: Article
• Language: English
• Published: Sociedade Brasileira de Química 2006-10-01
• Series: Química Nova
• Subjects: activation energy; fuel oil; thermogravimetry
• Online Access: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422006000500010&lng=en&tlng=en

Activation energy (Ea) is a parameter that can be applied to make predictions about the quality of oils to be used in an ICO engine. In this study, Ea was determined by thermogravimetry following two different procedures: ASTM E 1641 and Model-free kinetics. The energies were calculated in the low temperature oxidation (LTO) region for three Brazilian fuel oils (denominated A, B and C) and the results were equal using both methods: 43 kJ mol-1 (alpha=0.1 to 0.9) for oil A, 48 kJ mol-1 (alpha=0.1 to 0.5) and 65 kJ mol-1 (alpha=0.5 to 0.9) for oil B, and 58 kJ mol-1 (alpha=0.1 to 0.5) and 65 kJ mol-1 (alpha=0.5 to 0.9) for oil C. It was concluded that, among the oils studied, sample A was potentially the best option concerning the behavior in the LTO region.