Preparation of Alkaline Polyelectrolyte Membrane Based on Quaternary Ammonium Salt–Modified Cellulose and Its Application in Zn–Air Flexible Battery

• Main Authors: Xiang You, Congde Qiao, Dan Peng, Weiliang Liu, Cong Li, Hui Zhao, Hao Qi, Xiaoxia Cai, Yanqiu Shao, Xinhua Shi
• Format: Article
• Language: English
• Published: MDPI AG 2021-12-01
• Series: Polymers
• Subjects: microcrystalline cellulose; polyvinyl alcohol; quaternary ammonium salt; alkaline polyelectrolyte membrane; Zn–air battery
• Online Access: https://www.mdpi.com/2073-4360/13/1/9
• ISSN: 2073-4360

In this study, a type of alkaline solid polyelectrolyte (ASPE) membrane was developed via the introduction of microcrystalline cellulose (MCC) and its modified product (QMCC) into the polyvinyl alcohol (PVA) matrix. In this process, green NaOH/urea-based solvent was used to achieve a good dispersion of MCC in the PVA matrix; meanwhile, the OH⁻ groups in the NaOH/urea-based solvent provided an alkaline environment for good ion conductivity. Compared to the MCC-incorporated ASPE, further improved conductivity was achieved when the MCC was modified with quantitative quaternary ammonium salt. TGA showed that the addition of QMCC improved the water retention of the matrix, which was beneficial to the OH⁻ conduction in the system. Compared to the control (50 mS cm⁻¹), a maximum conductivity of 238 mS cm⁻¹ was obtained after the incorporation of QMCC in the PVA matrix. Moreover, the tensile strength of the polymer electrolyte were also significantly increased with the addition of QMCC. Finally, this developed ASPE membrane was used in assembling a flexible Zn–air battery and showed a promising potential in the development of flexible electronic devices.