Adsorption of hidrogen peroxide on the surface of silica – titania mixed oxide obtained by the sol-gel processing method

• Main Authors: José Eduardo Gonçalves, U. P. R. Filho, D. W. Franco, Yoshitaka Gushikem
• Format: Article
• Language: English
• Published: Universidade Estadual Paulista 2018-09-01
• Series: Eclética Química
• Online Access: https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/990

This work describes the sol-gel mixed oxide SiO 2 /TiO 2 property, ST, as prepared, and submitted to heat treatment a 773 K, STC. SEM and EDS images show, within magnification used, a uniform distribution of the TiO 2 particles in SiO 2 /TiO 2 matrix. Both, ST and STC adsorb hydrogen peroxide on the surface and through EPR and UV-Vis diffuse reflectance spectra, it was possible to conclude that the species on the surface is the peroxide molecule attached to the Lewis acid site of titanium particle surface, α Ti(H 2 O 2 ) + . As the material is very porous, presumably the hydrogen peroxide molecule is confined in the matrix pores on the surface, a reason why the adsorbed species presents an exceptional long lived stability.