Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)

Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)

In the title compound, [Tb(C15H11O2)3(C17H18N2)], the 7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline (LRR) ligand coordinates to TbIII through the two N atoms of the heterocycle. The metal centre is also chelated by three deprotonated 1,3-diphenylpropane-1,3-dione (dbm) ligand...

Full description

Bibliographic Details
Main Authors: Lei-Qi Chen, Jian-Nan Guo, Wei-Min Xuan, Yi-Ji Lin, Hui Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2009-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809019783
id doaj-5522b167991c440f992d85b5590f84f1
record_format Article
spelling doaj-5522b167991c440f992d85b5590f84f12020-11-25T01:05:13ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m705m70510.1107/S1600536809019783Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)Lei-Qi ChenJian-Nan GuoWei-Min XuanYi-Ji LinHui ZhangIn the title compound, [Tb(C15H11O2)3(C17H18N2)], the 7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline (LRR) ligand coordinates to TbIII through the two N atoms of the heterocycle. The metal centre is also chelated by three deprotonated 1,3-diphenylpropane-1,3-dione (dbm) ligands, forming enantiomerically pure [Tb(dbm)3LRR]. The TbIII atom is located in a distorted square antiprism of eight coordinating atoms (six O and two N atoms). http://scripts.iucr.org/cgi-bin/paper?S1600536809019783
collection DOAJ
language English
format Article
sources DOAJ
author Lei-Qi Chen
Jian-Nan Guo
Wei-Min Xuan
Yi-Ji Lin
Hui Zhang
spellingShingle Lei-Qi Chen
Jian-Nan Guo
Wei-Min Xuan
Yi-Ji Lin
Hui Zhang
Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)
Acta Crystallographica Section E
author_facet Lei-Qi Chen
Jian-Nan Guo
Wei-Min Xuan
Yi-Ji Lin
Hui Zhang
author_sort Lei-Qi Chen
title Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)
title_short Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)
title_full Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)
title_fullStr Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)
title_full_unstemmed Tris(dibenzoylmethanido-κ2O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2N,N′]terbium(III)
title_sort tris(dibenzoylmethanido-κ2o,o′)[(6r,8r)-(−)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ2n,n′]terbium(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-07-01
description In the title compound, [Tb(C15H11O2)3(C17H18N2)], the 7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline (LRR) ligand coordinates to TbIII through the two N atoms of the heterocycle. The metal centre is also chelated by three deprotonated 1,3-diphenylpropane-1,3-dione (dbm) ligands, forming enantiomerically pure [Tb(dbm)3LRR]. The TbIII atom is located in a distorted square antiprism of eight coordinating atoms (six O and two N atoms).
url http://scripts.iucr.org/cgi-bin/paper?S1600536809019783
work_keys_str_mv AT leiqichen trisdibenzoylmethanidoamp9542ooamp82426r8ramp872277dimethyl32pyridyl5678tetrahydro68methanoisoquinolineamp9542nnamp8242terbiumiii
AT jiannanguo trisdibenzoylmethanidoamp9542ooamp82426r8ramp872277dimethyl32pyridyl5678tetrahydro68methanoisoquinolineamp9542nnamp8242terbiumiii
AT weiminxuan trisdibenzoylmethanidoamp9542ooamp82426r8ramp872277dimethyl32pyridyl5678tetrahydro68methanoisoquinolineamp9542nnamp8242terbiumiii
AT yijilin trisdibenzoylmethanidoamp9542ooamp82426r8ramp872277dimethyl32pyridyl5678tetrahydro68methanoisoquinolineamp9542nnamp8242terbiumiii
AT huizhang trisdibenzoylmethanidoamp9542ooamp82426r8ramp872277dimethyl32pyridyl5678tetrahydro68methanoisoquinolineamp9542nnamp8242terbiumiii
_version_ 1725195550866800640

Similar Items