Design and Synthesis of Hyperbranched Aromatic Polymers for Catalysis

Design and Synthesis of Hyperbranched Aromatic Polymers for Catalysis

Aromatic polymers such as poly(ether sulfone), poly(ether ketone), and polyimide have been widely used in industry due to their thermal, mechanical, and chemical stabilities. Although their application to catalysis has been limited, the introduction of a hyperbranched architecture to such aromatic p...

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Main Authors: Yuta Nabae, Masa-aki Kakimoto
Format: Article
Language:English
Published: MDPI AG 2018-12-01
Series:Polymers
Subjects:
hyperbranched polymer
aromatic polymer
solid acid catalyst
partial oxidation
AB<sub>2</sub> monomer
A<sub>2</sub> + B<sub>3</sub> polymerization
heterogeneous catalyst
polycondensation
Online Access:https://www.mdpi.com/2073-4360/10/12/1344
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spelling doaj-54e7088324824e899ff683fd08a95a502020-11-24T23:57:19ZengMDPI AGPolymers2073-43602018-12-011012134410.3390/polym10121344polym10121344Design and Synthesis of Hyperbranched Aromatic Polymers for CatalysisYuta Nabae0Masa-aki Kakimoto1Department of Materials Science and Engineering, Tokyo Institute of Technology, 2-12-1 S8-26 Ookayama, Meguro-ku, Tokyo 152-8552, JapanDepartment of Materials Science and Engineering, Tokyo Institute of Technology, 2-12-1 S8-26 Ookayama, Meguro-ku, Tokyo 152-8552, JapanAromatic polymers such as poly(ether sulfone), poly(ether ketone), and polyimide have been widely used in industry due to their thermal, mechanical, and chemical stabilities. Although their application to catalysis has been limited, the introduction of a hyperbranched architecture to such aromatic polymers is effective in developing catalytic materials that combine the advantages of homogenous and heterogeneous catalysts. This review article overviews the recent progress on the design and synthesis of hyperbranched aromatic polymers. Several acid catalyzed reactions and the aerobic oxidation of alcohols have been demonstrated using hyperbranched aromatic polymers as catalysts. The advantage of hyperbranched polymers against linear polymers is also discussed.https://www.mdpi.com/2073-4360/10/12/1344hyperbranched polymeraromatic polymersolid acid catalystpartial oxidationAB<sub>2</sub> monomerA<sub>2</sub> + B<sub>3</sub> polymerizationheterogeneous catalystpolycondensation
collection DOAJ
language English
format Article
sources DOAJ
author Yuta Nabae
Masa-aki Kakimoto
spellingShingle Yuta Nabae
Masa-aki Kakimoto
Design and Synthesis of Hyperbranched Aromatic Polymers for Catalysis
Polymers
hyperbranched polymer
aromatic polymer
solid acid catalyst
partial oxidation
AB<sub>2</sub> monomer
A<sub>2</sub> + B<sub>3</sub> polymerization
heterogeneous catalyst
polycondensation
author_facet Yuta Nabae
Masa-aki Kakimoto
author_sort Yuta Nabae
title Design and Synthesis of Hyperbranched Aromatic Polymers for Catalysis
title_short Design and Synthesis of Hyperbranched Aromatic Polymers for Catalysis
title_full Design and Synthesis of Hyperbranched Aromatic Polymers for Catalysis
title_fullStr Design and Synthesis of Hyperbranched Aromatic Polymers for Catalysis
title_full_unstemmed Design and Synthesis of Hyperbranched Aromatic Polymers for Catalysis
title_sort design and synthesis of hyperbranched aromatic polymers for catalysis
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2018-12-01
description Aromatic polymers such as poly(ether sulfone), poly(ether ketone), and polyimide have been widely used in industry due to their thermal, mechanical, and chemical stabilities. Although their application to catalysis has been limited, the introduction of a hyperbranched architecture to such aromatic polymers is effective in developing catalytic materials that combine the advantages of homogenous and heterogeneous catalysts. This review article overviews the recent progress on the design and synthesis of hyperbranched aromatic polymers. Several acid catalyzed reactions and the aerobic oxidation of alcohols have been demonstrated using hyperbranched aromatic polymers as catalysts. The advantage of hyperbranched polymers against linear polymers is also discussed.
topic hyperbranched polymer
aromatic polymer
solid acid catalyst
partial oxidation
AB<sub>2</sub> monomer
A<sub>2</sub> + B<sub>3</sub> polymerization
heterogeneous catalyst
polycondensation
url https://www.mdpi.com/2073-4360/10/12/1344
work_keys_str_mv AT yutanabae designandsynthesisofhyperbranchedaromaticpolymersforcatalysis
AT masaakikakimoto designandsynthesisofhyperbranchedaromaticpolymersforcatalysis
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