2-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene

2-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene

In the title compound, C55H69BrO4, the calixarene molecule displays a `partial cone' conformation bearing the lateral substituent in a sterically favorable equatorial arrangement between two syn-orientated arene units. The crystal packing is stabilized by weak C—H...π...

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Main Authors: Conrad Fischer, Guisheng Lin, Wilhelm Seichter, Edwin Weber
Format: Article
Language:English
Published: International Union of Crystallography 2009-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809023137
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spelling doaj-54dadb9c558f422ab3ff8187310462732020-11-25T02:15:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657o1704o170410.1107/S16005368090231372-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]areneConrad FischerGuisheng LinWilhelm SeichterEdwin WeberIn the title compound, C55H69BrO4, the calixarene molecule displays a `partial cone' conformation bearing the lateral substituent in a sterically favorable equatorial arrangement between two syn-orientated arene units. The crystal packing is stabilized by weak C—H...π contacts, involving one tert-butyl group, and π–stacking interactions of the lateral bromobenzene units [centroid–centroid distance = 3.706 (1) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536809023137
collection DOAJ
language English
format Article
sources DOAJ
author Conrad Fischer
Guisheng Lin
Wilhelm Seichter
Edwin Weber
spellingShingle Conrad Fischer
Guisheng Lin
Wilhelm Seichter
Edwin Weber
2-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene
Acta Crystallographica Section E
author_facet Conrad Fischer
Guisheng Lin
Wilhelm Seichter
Edwin Weber
author_sort Conrad Fischer
title 2-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene
title_short 2-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene
title_full 2-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene
title_fullStr 2-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene
title_full_unstemmed 2-(4-Bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene
title_sort 2-(4-bromobenzyl)-5,11,17,23-tetra-tert-butyl-25,26,27,28-tetramethoxycalix[4]arene
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-07-01
description In the title compound, C55H69BrO4, the calixarene molecule displays a `partial cone' conformation bearing the lateral substituent in a sterically favorable equatorial arrangement between two syn-orientated arene units. The crystal packing is stabilized by weak C—H...π contacts, involving one tert-butyl group, and π–stacking interactions of the lateral bromobenzene units [centroid–centroid distance = 3.706 (1) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536809023137
work_keys_str_mv AT conradfischer 24bromobenzyl5111723tetratertbutyl25262728tetramethoxycalix4arene
AT guishenglin 24bromobenzyl5111723tetratertbutyl25262728tetramethoxycalix4arene
AT wilhelmseichter 24bromobenzyl5111723tetratertbutyl25262728tetramethoxycalix4arene
AT edwinweber 24bromobenzyl5111723tetratertbutyl25262728tetramethoxycalix4arene
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