(N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrate

(N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrate

The title compound, trans-[Co(C4H7N2O2)2Cl(C10H14N2S)]·0.5H2O, contains two independent molecules in the asymmetric unit in which the CoIII ions are coordinated in slightly distorted octahedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial site...

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Main Authors: C. Revathi, A. Dayalan, K. SethuSankar
Format: Article
Language:English
Published: International Union of Crystallography 2009-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809022661
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spelling doaj-5494ed30a5134b4681f8c4d08191ba182020-11-24T20:48:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m795m79610.1107/S1600536809022661(N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrateC. RevathiA. DayalanK. SethuSankarThe title compound, trans-[Co(C4H7N2O2)2Cl(C10H14N2S)]·0.5H2O, contains two independent molecules in the asymmetric unit in which the CoIII ions are coordinated in slightly distorted octahedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O—H...O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each molecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water molecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2). http://scripts.iucr.org/cgi-bin/paper?S1600536809022661
collection DOAJ
language English
format Article
sources DOAJ
author C. Revathi
A. Dayalan
K. SethuSankar
spellingShingle C. Revathi
A. Dayalan
K. SethuSankar
(N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrate
Acta Crystallographica Section E
author_facet C. Revathi
A. Dayalan
K. SethuSankar
author_sort C. Revathi
title (N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrate
title_short (N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrate
title_full (N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrate
title_fullStr (N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrate
title_full_unstemmed (N4-n-Butylpyridine-4-carbothioamide-κN4)chloridobis(dimethylglyoximato-κ2N,N′)cobalt(III) hemihydrate
title_sort (n4-n-butylpyridine-4-carbothioamide-κn4)chloridobis(dimethylglyoximato-κ2n,n′)cobalt(iii) hemihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-07-01
description The title compound, trans-[Co(C4H7N2O2)2Cl(C10H14N2S)]·0.5H2O, contains two independent molecules in the asymmetric unit in which the CoIII ions are coordinated in slightly distorted octahedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O—H...O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each molecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water molecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2).
url http://scripts.iucr.org/cgi-bin/paper?S1600536809022661
work_keys_str_mv AT crevathi n4nbutylpyridine4carbothioamideamp954n4chloridobisdimethylglyoximatoamp9542nnamp8242cobaltiiihemihydrate
AT adayalan n4nbutylpyridine4carbothioamideamp954n4chloridobisdimethylglyoximatoamp9542nnamp8242cobaltiiihemihydrate
AT ksethusankar n4nbutylpyridine4carbothioamideamp954n4chloridobisdimethylglyoximatoamp9542nnamp8242cobaltiiihemihydrate
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