Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.

Bibliographic Details
Main Authors:	Malgorzata Adamkiewicz, David O’Hagan, Georg Hähner
Format:	Article
Language:	English
Published:	Beilstein-Institut 2014-12-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	difluoro- dichloro- dibromomethylenecyclopropanes dihalocarbenes self-assembled monolayers surface coating
Online Access:	https://doi.org/10.3762/bjoc.10.307

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spelling	doaj-5492c6f6468849c19ff94a305cc330722021-02-02T01:57:45ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972014-12-011012897290210.3762/bjoc.10.3071860-5397-10-307Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)Malgorzata Adamkiewicz0David O’Hagan1Georg Hähner2EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife KY16 9ST, UKEaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife KY16 9ST, UKEaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife KY16 9ST, UKC11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.https://doi.org/10.3762/bjoc.10.307difluoro-dichloro-dibromomethylenecyclopropanesdihalocarbenesself-assembled monolayerssurface coating
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Malgorzata Adamkiewicz David O’Hagan Georg Hähner
spellingShingle	Malgorzata Adamkiewicz David O’Hagan Georg Hähner Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs) Beilstein Journal of Organic Chemistry difluoro- dichloro- dibromomethylenecyclopropanes dihalocarbenes self-assembled monolayers surface coating
author_facet	Malgorzata Adamkiewicz David O’Hagan Georg Hähner
author_sort	Malgorzata Adamkiewicz
title	Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_short	Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_full	Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_fullStr	Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_full_unstemmed	Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_sort	organic chemistry on surfaces: direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (sams)
publisher	Beilstein-Institut
series	Beilstein Journal of Organic Chemistry
issn	1860-5397
publishDate	2014-12-01
description	C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.
topic	difluoro- dichloro- dibromomethylenecyclopropanes dihalocarbenes self-assembled monolayers surface coating
url	https://doi.org/10.3762/bjoc.10.307
work_keys_str_mv	AT malgorzataadamkiewicz organicchemistryonsurfacesdirectcyclopropanationbydihalocarbeneadditiontovinylterminatedselfassembledmonolayerssams AT davidohagan organicchemistryonsurfacesdirectcyclopropanationbydihalocarbeneadditiontovinylterminatedselfassembledmonolayerssams AT georghahner organicchemistryonsurfacesdirectcyclopropanationbydihalocarbeneadditiontovinylterminatedselfassembledmonolayerssams
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Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

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