Influence of pH Adjustment Parameter for Sol–Gel Modification on Structural, Microstructure, and Magnetic Properties of Nanocrystalline Strontium Ferrite

• Main Authors: Raba’ah Syahidah Azis, Sakinah Sulaiman, Idza Riati Ibrahim, Azmi Zakaria, Jumiah Hassan, Nor Nadhirah Che Muda, Rodziah Nazlan, Norlaily M. Saiden, Yap Wing Fen, Muhammad Syazwan Mustaffa, Khamirul Amin Matori
• Format: Article
• Language: English
• Published: SpringerOpen 2018-05-01
• Series: Nanoscale Research Letters
• Subjects: Sol–gel; pH; Structural; Microstructure; Magnetic behavior; Strontium hexaferrite (SrFe12O19)
• Online Access: http://link.springer.com/article/10.1186/s11671-018-2562-x

Abstract Synthesis of nanocrystalline strontium ferrite (SrFe12O19) via sol–gel is sensitive to its modification parameters. Therefore, in this study, an attempt of regulating the pH as a sol–gel modification parameter during preparation of SrFe12O19 nanoparticles sintered at a low sintering temperature of 900 °C has been presented. The relationship of varying pH (pH 0 to 8) on structural, microstructures, and magnetic behaviors of SrFe12O19 nanoparticles were characterized by X-ray diffraction (XRD), field emission scanning microscope (FESEM), and vibrating sample magnetometer (VSM). Varying the pH of precursor exhibited a strong effect on the sintered density, crystal structure and magnetic properties of the SrFe12O19 nanoparticles. As the pH is 0, the SrFe12O19 produced relatively largest density, saturation magnetization, M s, and coercivity, H c, at a low sintering temperature of 900 °C. The grain size of SrFe12O19 is obtained in the range of 73.6 to 133.3 nm. The porosity of the sample affected the density and the magnetic properties of the SrFe12O19 ferrite. It is suggested that the low-temperature sintered SrFe12O19 at pH 0 displayed M s of 44.19 emu/g and H c of 6403.6 Oe, possessing a significant potential for applying in low-temperature co-fired ceramic permanent magnet.