Synthesis and structure of a complex of copper(I) with l-cysteine and chloride ions containing Cu12S6 nanoclusters

Synthesis and structure of a complex of copper(I) with l-cysteine and chloride ions containing Cu12S6 nanoclusters

The title hydrated copper(I)–l-cysteine–chloride complex has a polymeric structure of composition {[Cu16(CysH2)6Cl16]·xH2O}n [CysH2 = HO2CCH(NH3+)CH2S− or C3H7NO2S], namely, poly[[tetra-μ3-chlorido-deca-μ2-chlorido-dichloridohexakis(μ4-l-cysteinato)hexadecacopper] polyhydrate]. The copper atoms are...

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Bibliographic Details
Main Authors: Amir Gizatullin, Jonathan Becker, Daut Islamov, Nikita Serov, Siegfried Schindler, Alexander Klimovitskii, Valery Shtyrlin
Format: Article
Language:English
Published: International Union of Crystallography 2021-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cysteine
copper(i)
cage structure
squeeze procedure
metal–organic framework
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021002012

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