{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)

{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)

The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti(η2-Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}. The TiII atom is coordinated by two cyclopentadienyl (Cp) ligands and the...

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Main Authors: Martin Haehnel, Sven Hansen, Anke Spannenberg, Torsten Beweries
Format: Article
Language:English
Published: International Union of Crystallography 2013-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813014244
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spelling doaj-54436957ee424d2c95d91e9732e7e86b2020-11-24T20:47:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-06-01696m346m34610.1107/S1600536813014244{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)Martin HaehnelSven HansenAnke SpannenbergTorsten BeweriesThe title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti(η2-Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}. The TiII atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.http://scripts.iucr.org/cgi-bin/paper?S1600536813014244
collection DOAJ
language English
format Article
sources DOAJ
author Martin Haehnel
Sven Hansen
Anke Spannenberg
Torsten Beweries
spellingShingle Martin Haehnel
Sven Hansen
Anke Spannenberg
Torsten Beweries
{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)
Acta Crystallographica Section E
author_facet Martin Haehnel
Sven Hansen
Anke Spannenberg
Torsten Beweries
author_sort Martin Haehnel
title {N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)
title_short {N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)
title_full {N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)
title_fullStr {N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)
title_full_unstemmed {N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2P,P′}bis(η5-cyclopentadienyl)titanium(II)
title_sort {n,n-bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ2p,p′}bis(η5-cyclopentadienyl)titanium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-06-01
description The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti(η2-Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}. The TiII atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813014244
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AT svenhansen nnbisbis222trifluoroethoxyphosphanylmethylamine9542pp8242bis9515cyclopentadienyltitaniumii
AT ankespannenberg nnbisbis222trifluoroethoxyphosphanylmethylamine9542pp8242bis9515cyclopentadienyltitaniumii
AT torstenbeweries nnbisbis222trifluoroethoxyphosphanylmethylamine9542pp8242bis9515cyclopentadienyltitaniumii
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