6-Chloro-8-nitro-4-oxo-4H-chromene-3-carbaldehyde
In the title compound, C10H4ClNO5, the non-H atoms of the 6-chlorochromone unit are coplanar (r.m.s. deviation = 0.017 Å) with the largest deviation from the mean plane [0.031 (2) Å] being found for the C=O C atom. The nitro group (NO2) is inclined to the chromone unit mean plane by 13.3 (2) °. The...
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International Union of Crystallography
2014-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814007788 |
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doaj-54397893a2f04e05a74520822e73f2a92020-11-25T00:54:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-05-01705o547o54710.1107/S1600536814007788tk53056-Chloro-8-nitro-4-oxo-4H-chromene-3-carbaldehydeYoshinobu Ishikawa0School of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, JapanIn the title compound, C10H4ClNO5, the non-H atoms of the 6-chlorochromone unit are coplanar (r.m.s. deviation = 0.017 Å) with the largest deviation from the mean plane [0.031 (2) Å] being found for the C=O C atom. The nitro group (NO2) is inclined to the chromone unit mean plane by 13.3 (2) °. The formyl group is also twisted with respect to the attached ring [C—C—C—O torsion angles = 10.8 (4) and −171.8 (2)°]. In the crystal, molecules are linked via C-H...O hydrogen bonds forming slab-like networks lying parallel to (-301). The slabs are linked by π–π interactions involving the benzene rings of the chromone units [centroid–centroid distance = 3.770 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536814007788 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Yoshinobu Ishikawa |
| spellingShingle |
Yoshinobu Ishikawa 6-Chloro-8-nitro-4-oxo-4H-chromene-3-carbaldehyde Acta Crystallographica Section E |
| author_facet |
Yoshinobu Ishikawa |
| author_sort |
Yoshinobu Ishikawa |
| title |
6-Chloro-8-nitro-4-oxo-4H-chromene-3-carbaldehyde |
| title_short |
6-Chloro-8-nitro-4-oxo-4H-chromene-3-carbaldehyde |
| title_full |
6-Chloro-8-nitro-4-oxo-4H-chromene-3-carbaldehyde |
| title_fullStr |
6-Chloro-8-nitro-4-oxo-4H-chromene-3-carbaldehyde |
| title_full_unstemmed |
6-Chloro-8-nitro-4-oxo-4H-chromene-3-carbaldehyde |
| title_sort |
6-chloro-8-nitro-4-oxo-4h-chromene-3-carbaldehyde |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2014-05-01 |
| description |
In the title compound, C10H4ClNO5, the non-H atoms of the 6-chlorochromone unit are coplanar (r.m.s. deviation = 0.017 Å) with the largest deviation from the mean plane [0.031 (2) Å] being found for the C=O C atom. The nitro group (NO2) is inclined to the chromone unit mean plane by 13.3 (2) °. The formyl group is also twisted with respect to the attached ring [C—C—C—O torsion angles = 10.8 (4) and −171.8 (2)°]. In the crystal, molecules are linked via C-H...O hydrogen bonds forming slab-like networks lying parallel to (-301). The slabs are linked by π–π interactions involving the benzene rings of the chromone units [centroid–centroid distance = 3.770 (3) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536814007788 |
| work_keys_str_mv |
AT yoshinobuishikawa 6chloro8nitro4oxo4hchromene3carbaldehyde |
| _version_ |
1725234411942707200 |