Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate

Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate

The asymmetric unit of the title compound, [Cu(C4H8NO3)(C12H8N2)(H2O)]Cl·2H2O, contains a complex cation, a chloride anion and two water molecules. The CuII ion has a distorted square-pyramidal coordination geometry formed by one bidentate phenanthroline ligand, one O,N-bidentate dl-thr...

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Main Authors: Yi-Han Tan, Siang-Guan Teoh, Kei-Lin Sek, Wan-Sin Loh, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2010-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810015278
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spelling doaj-5422cedcb6fe428fb46bc24f0e62d0162020-11-24T21:21:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665m595m59610.1107/S1600536810015278Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrateYi-Han TanSiang-Guan TeohKei-Lin SekWan-Sin LohHoong-Kun FunThe asymmetric unit of the title compound, [Cu(C4H8NO3)(C12H8N2)(H2O)]Cl·2H2O, contains a complex cation, a chloride anion and two water molecules. The CuII ion has a distorted square-pyramidal coordination geometry formed by one bidentate phenanthroline ligand, one O,N-bidentate dl-threoninate ligand and one apical water molecule. In the crystal structure, intermolecular O—H...O, N—H...O, N—H...Cl and O—H...Cl hydrogen bonds link the components into layers. A single weak intermolecular C—H...O interaction connects these layers into a three-dimensional network. http://scripts.iucr.org/cgi-bin/paper?S1600536810015278
collection DOAJ
language English
format Article
sources DOAJ
author Yi-Han Tan
Siang-Guan Teoh
Kei-Lin Sek
Wan-Sin Loh
Hoong-Kun Fun
spellingShingle Yi-Han Tan
Siang-Guan Teoh
Kei-Lin Sek
Wan-Sin Loh
Hoong-Kun Fun
Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate
Acta Crystallographica Section E
author_facet Yi-Han Tan
Siang-Guan Teoh
Kei-Lin Sek
Wan-Sin Loh
Hoong-Kun Fun
author_sort Yi-Han Tan
title Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate
title_short Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate
title_full Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate
title_fullStr Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate
title_full_unstemmed Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate
title_sort aqua(1,10-phenanthroline-κ2n,n′)(dl-threoninato-κ2n,o1)copper(ii) chloride dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-05-01
description The asymmetric unit of the title compound, [Cu(C4H8NO3)(C12H8N2)(H2O)]Cl·2H2O, contains a complex cation, a chloride anion and two water molecules. The CuII ion has a distorted square-pyramidal coordination geometry formed by one bidentate phenanthroline ligand, one O,N-bidentate dl-threoninate ligand and one apical water molecule. In the crystal structure, intermolecular O—H...O, N—H...O, N—H...Cl and O—H...Cl hydrogen bonds link the components into layers. A single weak intermolecular C—H...O interaction connects these layers into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810015278
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AT siangguanteoh aqua110phenanthrolineamp9542nnamp8242dlthreoninatoamp9542no1copperiichloridedihydrate
AT keilinsek aqua110phenanthrolineamp9542nnamp8242dlthreoninatoamp9542no1copperiichloridedihydrate
AT wansinloh aqua110phenanthrolineamp9542nnamp8242dlthreoninatoamp9542no1copperiichloridedihydrate
AT hoongkunfun aqua110phenanthrolineamp9542nnamp8242dlthreoninatoamp9542no1copperiichloridedihydrate
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