catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]

catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]

The PbII atom in the polymeric title compound, [Pb(C8H4O4)(C12H6N2O2)]n, is chelated by the N-heterocycle, and adjacent atoms are bridged by rigid terephthalate dianions into a linear chain. The PbII atom is stereochemically active in a ψ-square-pyramidal coordination geometry in which...

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Main Authors: Zhen Wei, Feng-Yang Yu, Fang-Di Cong, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809046455
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spelling doaj-541186a65b4242bba59a493df19944172020-11-25T00:17:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1544m154410.1107/S1600536809046455catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]Zhen WeiFeng-Yang YuFang-Di CongSeik Weng NgThe PbII atom in the polymeric title compound, [Pb(C8H4O4)(C12H6N2O2)]n, is chelated by the N-heterocycle, and adjacent atoms are bridged by rigid terephthalate dianions into a linear chain. The PbII atom is stereochemically active in a ψ-square-pyramidal coordination geometry in which the lone-pair electrons occupy a basal site. When three other weaker Pb...O interactions are considered, the geometry is a ψ-dodecahedron. http://scripts.iucr.org/cgi-bin/paper?S1600536809046455
collection DOAJ
language English
format Article
sources DOAJ
author Zhen Wei
Feng-Yang Yu
Fang-Di Cong
Seik Weng Ng
spellingShingle Zhen Wei
Feng-Yang Yu
Fang-Di Cong
Seik Weng Ng
catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]
Acta Crystallographica Section E
author_facet Zhen Wei
Feng-Yang Yu
Fang-Di Cong
Seik Weng Ng
author_sort Zhen Wei
title catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]
title_short catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]
title_full catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]
title_fullStr catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline-5,6-dione-κ2N,N′)lead(II)]-μ-terephthalato-κ2O1:O4]
title_sort catena-poly[[(1,10-phenanthroline-5,6-dione-κ2n,n′)lead(ii)]-μ-terephthalato-κ2o1:o4]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description The PbII atom in the polymeric title compound, [Pb(C8H4O4)(C12H6N2O2)]n, is chelated by the N-heterocycle, and adjacent atoms are bridged by rigid terephthalate dianions into a linear chain. The PbII atom is stereochemically active in a ψ-square-pyramidal coordination geometry in which the lone-pair electrons occupy a basal site. When three other weaker Pb...O interactions are considered, the geometry is a ψ-dodecahedron.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809046455
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AT fengyangyu catenapoly110phenanthroline56dioneamp9542nnamp8242leadiiamp956terephthalatoamp9542o1o4
AT fangdicong catenapoly110phenanthroline56dioneamp9542nnamp8242leadiiamp956terephthalatoamp9542o1o4
AT seikwengng catenapoly110phenanthroline56dioneamp9542nnamp8242leadiiamp956terephthalatoamp9542o1o4
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