Solid-State Transformations in Inner Coordination Sphere of [Co(NH3)6][Fe(C2O4)3]∙3H2O as a Route to Access Catalytically Active Co-Fe Materials

Solid-State Transformations in Inner Coordination Sphere of [Co(NH3)6][Fe(C2O4)3]∙3H2O as a Route to Access Catalytically Active Co-Fe Materials

Thermal decomposition of [Co(NH3)6][Fe(C2O4)3]∙3H2O in argon atmosphere, at a low heating rate (3°/min), and in large amounts of the initial complex (~0.1 mole), has been studied. It was possible to distinguish four decomposition steps upon heating: In the temperature range of 50–1...

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Bibliographic Details
Main Authors: Denis P. Domonov, Sophia I. Pechenyuk, Yulia P. Semushina, Kirill V. Yusenko
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Materials
Subjects:
double complex salts
coordination sphere
catalyst
single-source precursor
thermal decomposition
Online Access:http://www.mdpi.com/1996-1944/12/2/221

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http://www.mdpi.com/1996-1944/12/2/221

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