Preparation of Advanced CuO Nanowires/Functionalized Graphene Composite Anode Material for Lithium Ion Batteries

The copper oxide (CuO) nanowires/functionalized graphene (f-graphene) composite material was successfully composed by a one-pot synthesis method. The f-graphene synthesized through the Birch reduction chemistry method was modified with functional group “–(CH2)5COOH”, and the CuO nanowires (NWs) were...

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Bibliographic Details
Main Authors: Jin Zhang, Beibei Wang, Jiachen Zhou, Ruoyu Xia, Yingli Chu, Jia Huang
Format: Article
Language:English
Published: MDPI AG 2017-01-01
Series:Materials
Subjects:
CuO
Online Access:http://www.mdpi.com/1996-1944/10/1/72
Description
Summary:The copper oxide (CuO) nanowires/functionalized graphene (f-graphene) composite material was successfully composed by a one-pot synthesis method. The f-graphene synthesized through the Birch reduction chemistry method was modified with functional group “–(CH2)5COOH”, and the CuO nanowires (NWs) were well dispersed in the f-graphene sheets. When used as anode materials in lithium-ion batteries, the composite exhibited good cyclic stability and decent specific capacity of 677 mA·h·g−1 after 50 cycles. CuO NWs can enhance the lithium-ion storage of the composites while the f-graphene effectively resists the volume expansion of the CuO NWs during the galvanostatic charge/discharge cyclic process, and provide a conductive paths for charge transportation. The good electrochemical performance of the synthesized CuO/f-graphene composite suggests great potential of the composite materials for lithium-ion batteries anodes.
ISSN:1996-1944