Reinforcement of Rubber Magnetic Composites with Zinc Salts of Acrylic and Methacrylic Acids

• Main Authors: Ján Kruželák, Viera Karlíková, Rastislav Dosoudil, Katarína Tomanová, Ivan Hudec
• Format: Article
• Language: English
• Published: MDPI AG 2018-11-01
• Series: Materials
• Subjects: strontium ferrite; rubber composites; peroxide cross-linking; co-agents
• Online Access: https://www.mdpi.com/1996-1944/11/11/2161

Strontium ferrite was compounded with acrylonitrile butadiene rubber to prepare rubber magnetic composites. For cross-linking of the prepared materials, peroxide curing systems consisting of dicumyl peroxide as curing agent and zinc salts of acrylic and methacrylic acids as co-agents were used. The amount of strontium ferrite was kept constant in all experiments, while the main objective of the work was to investigate the composition of curing system and both types of co-agents on the cross-linking, physical-mechanical, dynamic and magnetic properties of the rubber magnets. The results showed that the change in composition of curing system has significant influence on cross-link density and properties of the tested composite materials. With an increasing amount of zinc based co-agents, significant improvement of tensile strength was achieved. The application of zinc based co-agents in peroxide vulcanization of rubber magnetic composites leads to the preparation of rubber magnets with not only good magnetic properties, but also with improved physical-mechanical characteristics.