In situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiols

Supported hydrogen peroxide on polyvinylpolypyrrolidone (PVPH2O2), silica sulfuric acid (SiO2-OSO3H) and catalytic amounts of potassium iodide (KI) has been developed as a heterogeneous medium for the rapid oxidative coupling of thiols into symmetrical homodisulfides. This oxidizing system procee...

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Main Authors: Ghorbani-Choghamarani Arash, Nikoorazm Mohsen, Azadi Gouhar
Format: Article
Language:English
Published: Serbian Chemical Society 2013-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391200054G.pdf
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spelling doaj-5317edd4f1c44a09ae3d92275d9aa0b72020-11-24T22:47:51ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51392013-01-0178217317810.2298/JSC120223054GIn situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiolsGhorbani-Choghamarani ArashNikoorazm MohsenAzadi GouharSupported hydrogen peroxide on polyvinylpolypyrrolidone (PVPH2O2), silica sulfuric acid (SiO2-OSO3H) and catalytic amounts of potassium iodide (KI) has been developed as a heterogeneous medium for the rapid oxidative coupling of thiols into symmetrical homodisulfides. This oxidizing system proceeds under extremely mild conditions and gives no other oxidized side products.http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391200054G.pdfsupported hydrogen peroxide on polyvinylpolypyrrolidonepotassium iodide (KI)silica sulfuric acid (SiO2-OSO3H)
collection DOAJ
language English
format Article
sources DOAJ
author Ghorbani-Choghamarani Arash
Nikoorazm Mohsen
Azadi Gouhar
spellingShingle Ghorbani-Choghamarani Arash
Nikoorazm Mohsen
Azadi Gouhar
In situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiols
Journal of the Serbian Chemical Society
supported hydrogen peroxide on polyvinylpolypyrrolidone
potassium iodide (KI)
silica sulfuric acid (SiO2-OSO3H)
author_facet Ghorbani-Choghamarani Arash
Nikoorazm Mohsen
Azadi Gouhar
author_sort Ghorbani-Choghamarani Arash
title In situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiols
title_short In situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiols
title_full In situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiols
title_fullStr In situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiols
title_full_unstemmed In situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiols
title_sort in situ generated hypoiodous acid in an efficient and heterogeneous catalytic system for the homo-oxidative coupling of thiols
publisher Serbian Chemical Society
series Journal of the Serbian Chemical Society
issn 0352-5139
publishDate 2013-01-01
description Supported hydrogen peroxide on polyvinylpolypyrrolidone (PVPH2O2), silica sulfuric acid (SiO2-OSO3H) and catalytic amounts of potassium iodide (KI) has been developed as a heterogeneous medium for the rapid oxidative coupling of thiols into symmetrical homodisulfides. This oxidizing system proceeds under extremely mild conditions and gives no other oxidized side products.
topic supported hydrogen peroxide on polyvinylpolypyrrolidone
potassium iodide (KI)
silica sulfuric acid (SiO2-OSO3H)
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2013/0352-51391200054G.pdf
work_keys_str_mv AT ghorbanichoghamaraniarash insitugeneratedhypoiodousacidinanefficientandheterogeneouscatalyticsystemforthehomooxidativecouplingofthiols
AT nikoorazmmohsen insitugeneratedhypoiodousacidinanefficientandheterogeneouscatalyticsystemforthehomooxidativecouplingofthiols
AT azadigouhar insitugeneratedhypoiodousacidinanefficientandheterogeneouscatalyticsystemforthehomooxidativecouplingofthiols
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