Antibacterial, in vitro antitumor activity and structural studies of rhodium and iridium complexes featuring the two positional isomers of pyridine carbaldehyde picolinic hydrazone ligand

Half-sandwich organometallic rhodium and iridium complexes [1–6] have been synthesized with ligands L1 (L1 = Pyridin-2-ylmethylene picolinichydrazine) and L2 (L2 = Pyridin-3-ylmethylene picolinichydrazine). Treatment of [{Cp∗MCl2}2] (M = Rh/Ir) with L1 in methanol has yielded mononuclear cationic co...

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Bibliographic Details
Main Authors: Narasinga Rao Palepu, J. Richard Premkumar, Akalesh Kumar Verma, Kaushik Bhattacharjee, S.R. Joshi, Scott Forbes, Yurij Mozharivskyj, Kollipara Mohan Rao
Format: Article
Language:English
Published: Elsevier 2018-07-01
Series:Arabian Journal of Chemistry
Online Access:http://www.sciencedirect.com/science/article/pii/S187853521500307X