Bis(pentane-2,4-dionato)bis[2-(4-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide]nickel(II)

In the title compound, [Ni(C5H7O2)2(C12H16N3O2)], the NiII cation is hexacoordinated by four O and two N atoms, showing a slightly distorted octahedral geometry. The NiII cation lies on an inversion centre, as a consequence of which the asymmetric unit comprises one half-molecule. The four O atoms b...

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Bibliographic Details
Main Authors: Lujiang Hao, Chunhua Mu, Binbin Kong
Format: Article
Language:English
Published: International Union of Crystallography 2008-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808018552
Description
Summary:In the title compound, [Ni(C5H7O2)2(C12H16N3O2)], the NiII cation is hexacoordinated by four O and two N atoms, showing a slightly distorted octahedral geometry. The NiII cation lies on an inversion centre, as a consequence of which the asymmetric unit comprises one half-molecule. The four O atoms belonging to two pentane-2,4-dionate ligands lie in the equatorial plane and two pyridyl N atoms occupy the axial coordination sites.
ISSN:1600-5368